Experimental and Computational Investigation of Thiolate Alkylation in Ni II and Zn II Complexes: Role of the Metal on the Sulfur Nucleophilicity

Marcello Gennari (1) , Marius Retegan (2) , Serena Debeer (3) , Jacques Pécaut (4) , Frank Neese (5) , Marie-Noëlle Collomb (1) , Carole Duboc (1)

1 DCM - CIRE - Département de Chimie Moléculaire - Chimie Inorganique Redox
2 Max-Planck-Institut für Chemische Energie Konversion
3 Cornell University [New York]
4 RICC - Reconnaissance Ionique et Chimie de Coordination
5 MPI-CEC - Max-Planck-Institut für Chemische Energiekonversion

Domaines: Chimie

Marcello Gennari, Marius Retegan, Serena Debeer, Jacques Pécaut, Frank Neese, et al.. Experimental and Computational Investigation of Thiolate Alkylation in Ni II and Zn II Complexes: Role of the Metal on the Sulfur Nucleophilicity. Inorganic Chemistry, 2011, 50 (20), pp.10047 - 10055. ⟨10.1021/ic200899w⟩. ⟨hal-01655259⟩