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Is it easy to improve radiochemical methods in respect of REACH regulation?

Abstract : For more than twenty years, the LASE (Operator Support Analysis Laboratory) has been developing and implementing radiochemical methods devoted to the determination of Difficult To Measure radionuclides in radwaste. In particular, its expertise concerns the characterization of long-lived beta emitters such as $^{55}$Fe, $^{63}$Ni and $^{99}$Tc in various matrices. The purification procedures applied for a long time are highly selective towards those radionuclides but mainly based on liquid-liquid extraction steps including the use of chloroform which is restricted through REACH regulation . The elimination of this solvent is a real challenge for radioanalytical laboratories. Furthermore, the management of short-lived radioactive tracers such as $^{99m}$Tc is becoming difficult. Consequently, alternative radiochemical methods have to be investigated.The presentation will first focus on the results of speciation calculations (performed with Chess software) which are of prime interest to better understand the involved chemical processes and to optimize the alternative separation methods. The second part of the work will deal with the improvements made for the analysis of $^{55}$Fe, $^{63}$Ni and $^{99}$Tc. Extraction chromatography was introduced to maintain high decontamination factors towards the interfering elements. TRU, Ni and TEVA resins were respectively tested in the purification procedures dedicated to $^{55}$Fe, $^{63}$Ni and $^{99}$Tc measurements. In order to increase the responsiveness of the laboratory, the implementation of rhenium instead of $^{99m}$Tc as tracer was also investigated. The results will be compared in terms of separation yield, selectivity and accuracy for real radioactive waste and effluents. In the future, this approach can be extended to other radionuclides such as $^{93}$Zr.
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Submitted on : Thursday, January 16, 2020 - 1:37:30 PM
Last modification on : Tuesday, April 28, 2020 - 11:28:16 AM

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  • HAL Id : hal-02442258, version 1

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C. Gautier, C. Colin, J. Degros, P. Perret, C. Cruchet, et al.. Is it easy to improve radiochemical methods in respect of REACH regulation?. NRC9 - 9th international conference on nuclear and radiochemistry, Aug 2016, Helsinki, Finland. ⟨hal-02442258⟩

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