Swollen cubic phases with reduced hardness solubilizing a model fragrance oil as a co-surfactant

Vera Tchakalova (1) , Thomas Zemb (2) , Fabienne Testard (3)

1 Firmenich Recherche et Développement
2 ICSM - UMR 5257 - Institut de Chimie Séparative de Marcoule
3 LIONS - Laboratoire Interdisciplinaire sur l'Organisation Nanométrique et Supramoléculaire

Swollen cubic lyotropic ternary phases with Pn3m symmetry and reduced hardness were obtained from a specific binary mixture of cubic phase-forming (phytantriol) and lamellar phase-forming (decaglycerol monooleate) compounds. The microstructures were determined by using a small-angle X-ray scattering technique. The softness and temperature-induced phase transitions were investigated by means of rheology. The incorporation of a surface-active fragrance compound (linalool) at concentrations up to 6%wt induced a structural transition toward a softer Im3m bulk cubic phase with longer water channels. Higher linalool concentrations allowed the spontaneous dispersion of the bulk cubic phase into microscopic particles with a cubic structure (cubosomes).

Domaines: Matériaux

Vera Tchakalova, Thomas Zemb, Fabienne Testard. Swollen cubic phases with reduced hardness solubilizing a model fragrance oil as a co-surfactant. Journal of Chemical Physics, 2022, ⟨10.1063/5.0124021⟩. ⟨cea-03857516⟩