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Syn-cryptophanes: macrocyclic compounds with optimized characteristics for the design of 129 Xe NMR-based biosensors

Estelle Léonce 1 Thierry Brotin 2 Patrick Berthault 1 
1 LSDRM - Laboratoire Structure et Dynamique par Résonance Magnétique (LCF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : A new water-soluble xenon host system with great promise for the 129 Xe NMR-based biosensing approach is presented: the syn-cryptophane-222-hexacarboxylate. It compares favorably with its already known anti diastereomer, on the one hand, and with cucurbit[6]uril, on the other hand, in particular in terms of xenon binding constant and xenon in-out exchange, a key parameter for the efficiency of the most sensitive HyperCEST method.
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https://hal-cea.archives-ouvertes.fr/cea-03807625
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Monday, October 10, 2022 - 8:38:59 AM
Last modification on : Sunday, November 27, 2022 - 11:20:10 AM

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Estelle Léonce, Thierry Brotin, Patrick Berthault. Syn-cryptophanes: macrocyclic compounds with optimized characteristics for the design of 129 Xe NMR-based biosensors. Physical Chemistry Chemical Physics, 2022, 24, pp.24793-24799. ⟨10.1039/x0xx00000x⟩. ⟨cea-03807625⟩

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