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Phenomenological statistics of diluted charged solutions

Ioulia Chikina 1 
1 LIONS - Laboratoire Interdisciplinaire sur l'Organisation Nanométrique et Supramoléculaire
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : The consistent interpretation of the equilibrium and simplest transport properties of diluted liquid electrolytes, the normal and cryogenic ones, by analogy with the observed consequences of electron-hole statistics in crystal-line semiconductors is proposed. The consideration is based on the microcharacteristics of individual charged clusters, introduced phenomenologically, such as their energies, effective masses, etc. The possibilities of ex-tracting these parameters from the available experimental data are discussed in detail. This is crucial for explain-ing the very possibility of the statisticalconsideration of what is unfolding in electrolytes. A deep analogy be-tween the statistics of electrolytes and that of solid-state semiconductors is noted. Its presence is the basis of the phenomenology being developed
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Submitted on : Monday, July 4, 2022 - 7:54:27 AM
Last modification on : Wednesday, July 6, 2022 - 4:09:04 AM


  • HAL Id : cea-03712516, version 1


Ioulia Chikina. Phenomenological statistics of diluted charged solutions. Fizika Nizkikh Temperatur, 2022, 48, pp.674-691. ⟨cea-03712516⟩



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