Phenomenological statistics of diluted charged solutions
Résumé
The consistent interpretation of the equilibrium and simplest transport properties of diluted liquid electrolytes, the normal and cryogenic ones, by analogy with the observed consequences of electron-hole statistics in crystal-line semiconductors is proposed. The consideration is based on the microcharacteristics of individual charged clusters, introduced phenomenologically, such as their energies, effective masses, etc. The possibilities of ex-tracting these parameters from the available experimental data are discussed in detail. This is crucial for explain-ing the very possibility of the statisticalconsideration of what is unfolding in electrolytes. A deep analogy be-tween the statistics of electrolytes and that of solid-state semiconductors is noted. Its presence is the basis of the phenomenology being developed