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Communication Dans Un Congrès Année : 2022

Operando analysis and monitoring of lithium in Li-ion batteries using nuclear microanalysis

Résumé

Lithium-ion technology holds a prominent place in the battery’s area. Although its energy densities increased and the number of cycles raised as high as thousands, it still needs vast improvements to meet ever-greater demands regarding autonomy, lifespan, safety and miniaturization. Capacity fading during cycling remains a major problem limiting battery lifetime. It is therefore necessary to understand the origin of aging phenomena leading to loss of electrochemical performance in order to guide research towards new materials. For this, many in situ / operando studies have been developed (XPS, MET, NMR, XRD ...)[1]. However, none of the techniques mentioned can directly detect the lithium element, which makes the visualization and quantification of all the lithium present in an electrode or a battery impossible. Nuclear microanalysis is a technique capable of giving quantitative and qualitative information on spatial distributions of light elements such as lithium [2]. It is therefore a tool with great potential for understanding the mechanisms in lithium insertion materials. In previous ex situ studies, we showed immobilization of lithium in the LiFePO4 electrode during the first charge / discharge cycles [3]. We further developed an electrochemical cell coupled to the nuclear microprobe to perform in situ / operando analyzes[4].The cell is capable of providing electrochemical performances comparable to those obtained with conventional electrochemical cells on the first two cycles. We thus observed operando the formation of a SEI layer at the electrode / electrolyte interface and the trapping of lithium in a LiFePO4 // LiPF6 in EC-DEC // graphite assembly. The use of a liquid electrolyte creates complications for the analyses: it flows from the assembly to the cell window, rendering the interpretation of results difficult. The use of solid electrolyte in all solid-state batteries should give more information about the parasite electrochemical reaction (composition and thickness).
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Dates et versions

cea-03672281 , version 1 (19-05-2022)

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  • HAL Id : cea-03672281 , version 1

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S Surblé, C Paireau, M Gauthier, H Khodja, J-F Martin. Operando analysis and monitoring of lithium in Li-ion batteries using nuclear microanalysis. International Operando Battery Days, May 2022, Grenoble, France. ⟨cea-03672281⟩
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