Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones - CEA - Commissariat à l’énergie atomique et aux énergies alternatives Access content directly
Journal Articles Chemical Communications Year : 2022

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

Abstract

A transfer hydrosilylation of ketones employing silyl formates as hydrosilane surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61–99% yields in the presence of a PNHP-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated.
Fichier principal
Vignette du fichier
Romero_ChemComm2022_V0.pdf (1.29 Mo) Télécharger le fichier
Origin : Files produced by the author(s)

Dates and versions

cea-03662659 , version 1 (05-10-2022)

Licence

Attribution

Identifiers

Cite

R. Martin Romero, Neethu Thyagarajan, Nora Hellou, Clément Chauvier, Timothé Godou, et al.. Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones. Chemical Communications, 2022, 58, pp.6308-6311. ⟨10.1039/D2CC00666A⟩. ⟨cea-03662659⟩
26 View
8 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More