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Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

R. Martin Romero 1 Neethu Thyagarajan 1 Nora Hellou 1 Clément Chauvier 1 Timothé Godou 1 Lucile Anthore-Dalion 1 Thibault Cantat 1 
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : A transfer hydrosilylation of ketones employing silyl formates as hydrosilane surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61–99% yields in the presence of a PNHP-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated.
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https://hal-cea.archives-ouvertes.fr/cea-03662659
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Submitted on : Monday, May 9, 2022 - 2:43:53 PM
Last modification on : Monday, May 30, 2022 - 7:57:16 AM

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R. Martin Romero, Neethu Thyagarajan, Nora Hellou, Clément Chauvier, Timothé Godou, et al.. Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones. Chemical Communications, Royal Society of Chemistry, 2022, 58, pp.6308-6311. ⟨10.1039/D2CC00666A⟩. ⟨cea-03662659⟩

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