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Reductive depolymerization of polyesters and polycarbonates with hydroboranes by using a lanthanum(III) tris(amide) catalyst

Thibault Cantat 1 Jean-Claude Berthet 1 Marie Kobylarski 1 
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : The homogeneous reductive depolymerization of polyesters and polycarbonates with hydroboranes is achieved with the use of an f-metal complex catalyst. These polymeric materials are transformed into their value-added alcohol equivalents. Catalysis proceeds readily, under mild conditions, with La[N(SiMe$_3$)$_2$]$_3$ (1 mol%) and pinacolborane (HBpin) and shows high selectivity towards alcohols and diols, after hydrolysis.
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https://hal-cea.archives-ouvertes.fr/cea-03559538
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Submitted on : Monday, February 7, 2022 - 7:23:01 AM
Last modification on : Tuesday, March 1, 2022 - 10:10:31 AM
Long-term archiving on: : Sunday, May 8, 2022 - 6:13:39 PM

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Thibault Cantat, Jean-Claude Berthet, Marie Kobylarski. Reductive depolymerization of polyesters and polycarbonates with hydroboranes by using a lanthanum(III) tris(amide) catalyst. Chemical Communications, Royal Society of Chemistry, 2022, 58, pp.2830-2833. ⟨10.1039/D2CC00184E⟩. ⟨cea-03559538⟩

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