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Trivalent actinides/lanthanides separation using bis-triazinyl-pyridines

Abstract

The separation of trivalent minor actinides from trivalent lanthanides is a difficult task. The present paper describes the application of a Bis-Triazinyl-Pyridine in order to separate americium(III) and curium(III) from various lanthanides(III) present in a synthetic aqueous feed solution simulating a stripping solution issued from the DIAMEX process. The performances observed during the counter-current alpha hot test, carried out at CEA Marcoule using two batteries of eight mixer-settlers, are very promising. They remain, up to now, the best An(III)/Ln(III) separation results ever obtained at such a high acidity ([HNO 3 ] initial = 1 mol/L).
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Dates and versions

cea-03541542 , version 1 (24-01-2022)

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  • HAL Id : cea-03541542 , version 1

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Clément Hill, Xavier Hérès, Jean-Noël Calor, Denis Guillaneux, Bernard Mauborgne, et al.. Trivalent actinides/lanthanides separation using bis-triazinyl-pyridines. GLOBAL 1999, Aug 1999, Jackson Hole, United States. ⟨cea-03541542⟩

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