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Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones
Abstract : An energetically and atom economic transfer hydrosilylation of ketones employing silyl formates as hydrosilanes surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61-99% yield in the presence of a PNHP-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated.
https://hal-cea.archives-ouvertes.fr/cea-03527966
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Monday, January 17, 2022 - 7:10:22 AM
Last modification on : Wednesday, January 19, 2022 - 3:31:18 AM
Long-term archiving on: : Monday, April 18, 2022 - 6:12:57 PM
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Monday, January 17, 2022 - 7:10:22 AM
Last modification on : Wednesday, January 19, 2022 - 3:31:18 AM
Long-term archiving on: : Monday, April 18, 2022 - 6:12:57 PM
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Romero_Silyl2022_V0.pdf
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