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Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

R. Martin Romero 1 Nora Hellou 1 Clément Chauvier 1 Timothé Godou 1 Lucile Anthore-Dalion 1 Thibault Cantat 1
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : An energetically and atom economic transfer hydrosilylation of ketones employing silyl formates as hydrosilanes surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61-99% yield in the presence of a PNHP-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated.
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Preprints, Working Papers, ...
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Submitted on : Monday, January 17, 2022 - 7:10:22 AM
Last modification on : Wednesday, January 19, 2022 - 3:31:18 AM
Long-term archiving on: : Monday, April 18, 2022 - 6:12:57 PM


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R. Martin Romero, Nora Hellou, Clément Chauvier, Timothé Godou, Lucile Anthore-Dalion, et al.. Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones. 2022. ⟨cea-03527966⟩



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