Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst - Archive ouverte HAL Access content directly
Journal Articles Catalysis Science & Technology Year : 2021

Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst

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Abstract

Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines to methylamines. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In$_2$O$_3$ catalyst without the need for any additive.
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Dates and versions

cea-03478547 , version 1 (14-12-2021)

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Caroline Genre, Idir Benaissa, Timothé Godou, Mathieu Pinault, Thibault Cantat. Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst. Catalysis Science & Technology, In press, 12, pp.57-61. ⟨10.1039/D1CY01626A⟩. ⟨cea-03478547⟩
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