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Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst

Caroline Genre 1 Idir Benaissa 1 Timothé Godou 1 Mathieu Pinault 2 Thibault Cantat 1
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
2 LEDNA - Laboratoire Edifices Nanométriques
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines to methylamines. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In$_2$O$_3$ catalyst without the need for any additive.
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https://hal-cea.archives-ouvertes.fr/cea-03478547
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Submitted on : Tuesday, December 14, 2021 - 7:17:44 AM
Last modification on : Wednesday, January 12, 2022 - 11:16:29 AM

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Caroline Genre, Idir Benaissa, Timothé Godou, Mathieu Pinault, Thibault Cantat. Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst. Catalysis Science & Technology, Royal Society of Chemistry, In press, 12, pp.57-61. ⟨10.1039/D1CY01626A⟩. ⟨cea-03478547⟩

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