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Additive-free selective methylation of amines with formic acid over a Pd/In$_2$O$_3$ catalyst

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Abstract

Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines to methylamines. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In$_2$O$_3$ catalyst without the need for any additive.
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cea-03353696 , version 1 (24-09-2021)

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Attribution - NonCommercial - NoDerivatives - CC BY 4.0

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Caroline Genre, Idir Benaissa, Timothé Godou, Mathieu Pinault, Thibault Cantat. Additive-free selective methylation of amines with formic acid over a Pd/In$_2$O$_3$ catalyst. 2021. ⟨cea-03353696⟩
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