Skip to Main content Skip to Navigation
Conference papers

Interlayers for Cr-coated nuclear fuel claddings: Preliminary study of Mo

Abstract : Grown with an adequate process, an external Cr coating undeniably improves the robustness of zirconium-based nuclear fuel claddings, especially upon hypothetical high temperature accident conditions such as Loss-of-Coolant-Accident (LOCA) [1, 2]. However, beyond design-based-accident conditions encountered above 1200°C, the Cr-Zr binary system is subject to interdiffusion [3]. In addition to decreasing the Cr quantity available for the protection against high-temperature oxidation by forming an outer Cr2O3 layer, interdiffusion induces Cr-Zr eutectic reaction above 1300°C [3]. One solution to mitigate this effect and increase even more the resistance of Cr-coated claddings in LOCA (and beyond) conditions, is the deposition of an interlayer between the Cr coating and the Zr-based substrate, acting as a diffusion barrier. This paper covers briefly the identification and selection criteria of a relevant interlayer material in connection with its deposition process. A case study is detailed with the deposition of a Mo interlayer by magnetron sputtering, topped by a Cr layer (around 12 µm) on zirconium flat coupons. The beneficial effect of the Mo interlayer thickness (2 and 4 µm) on the performances of the coated Zr-based substrates is discussed regarding high-temperature oxidation tests in dry and wet air. Additionally, microstructural investigations are carried out after and before the tests to get more insights into the bilayer Cr-Mo coated Zr substrate evolution at high temperature.
Document type :
Conference papers
Complete list of metadata
Contributor : Contributeur MAP CEA Connect in order to contact the contributor
Submitted on : Wednesday, September 15, 2021 - 2:30:11 PM
Last modification on : Sunday, June 26, 2022 - 12:31:03 AM
Long-term archiving on: : Thursday, December 16, 2021 - 6:56:48 PM


Files produced by the author(s)


  • HAL Id : cea-03345302, version 1


Alexandre Michau, Michael Ougier, Thomas Guilbert, Jérémy Bischoff, Edouard Pouillier, et al.. Interlayers for Cr-coated nuclear fuel claddings: Preliminary study of Mo. NuMat2020 - The Nuclear Materials Conference, Oct 2020, Ghent, Belgium. ⟨cea-03345302⟩



Record views


Files downloads