 |
A copper(I)-catalyzed sulfonylative Hiyama cross-coupling
Abstract : An air-tolerant Cu-catalyzed sulfonylative Hiyama cross-coupling reaction enabling the formation of diaryl sulfones is described. Starting from aryl silanes, DABSO and aryliodides, the reaction tolerates a large variety of polar functional groups (amines, ketones, esters, aldehydes). Control experiments coupled with DFT calculations shed light on the mechanism, where the reductive elimination showcases an usual high energy barrier for a Cu(III)/Cu(I) process.
https://hal-cea.archives-ouvertes.fr/cea-03284987
Contributor : Serge Palacin <>
Submitted on : Tuesday, July 13, 2021 - 7:07:58 AM
Last modification on : Thursday, July 15, 2021 - 3:33:39 AM
Contributor : Serge Palacin <>
Submitted on : Tuesday, July 13, 2021 - 7:07:58 AM
Last modification on : Thursday, July 15, 2021 - 3:33:39 AM
File
Adenot_Chemrxiv2021_V0.pdf
Publisher files allowed on an open archive
Licence
Distributed under a Creative Commons Attribution - NonCommercial - NoDerivatives 4.0 International License