Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases - Archive ouverte HAL Access content directly
Preprints, Working Papers, ... Year :

Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases

(1) , (1) , (1) , (1)
1

Abstract

The efficient synthesis of hydrosilanes by catalytic ydrogenolysis of chlorosilanes is described, using an Iridum (III) pincer catalyst. A careful selection of a nitrogen base (incl. sterically hindered guanidines and phosphazenes) can unlock the preparation of Me3SiH, Et3SiH and Me2SiHCl in high yield (up to 98%), directly from their corresponding chlorosilanes.
Fichier principal
Vignette du fichier
ChemXRiv2021_Durin.pdf (751.43 Ko) Télécharger le fichier
Origin : Files produced by the author(s)

Dates and versions

cea-03204999 , version 1 (22-04-2021)

Licence

Attribution - NonCommercial - NoDerivatives - CC BY 4.0

Identifiers

Cite

Gabriel Durin, Jean-Claude Berthet, Emmanuel Nicolas, Thibault Cantat. Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases. 2021. ⟨cea-03204999⟩
25 View
68 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More