J. Heinze, Ultramicroelectrodes in Electrochemistry, Angewandte Chemie International Edition in English, vol.32, issue.9, pp.1268-1288, 1993.

A. Dobrzeniecka, A. Zeradjanin, J. Masa, A. Puschhof, J. Stroka et al., Application of SECM in tracing of hydrogen peroxide at multicomponent non-noble electrocatalyst films for the oxygen reduction reaction, Catalysis Today, vol.202, pp.55-62, 2013.

A. S. Aricò, P. Bruce, B. Scrosati, J. M. Tarascon, and W. Van-schalkwijk, Nanostructured materials for advanced energy conversion and storage devices, Nature Materials, vol.4, issue.5, pp.366-377, 2005.

Y. Yu, T. Sun, and M. V. Mirkin, Scanning Electrochemical Microscopy of Single Spherical Nanoparticles: Theory and Particle Size Evaluation, Analytical Chemistry, vol.87, issue.14, pp.7446-7453, 2015.

C. M. Sánchez-sánchez, J. Rodríguez-lópez, and A. J. Bard, Scanning Electrochemical Microscopy. 60. Quantitative Calibration of the SECM Substrate Generation/Tip Collection Mode and Its Use for the Study of the Oxygen Reduction Mechanism, Analytical Chemistry, vol.80, issue.9, pp.3254-3260, 2008.

A. Minguzzi, M. A. Alpuche-aviles, J. R. López, S. Rondinini, and A. J. Bard, Screening of Oxygen Evolution Electrocatalysts by Scanning Electrochemical Microscopy Using a Shielded Tip Approach, Analytical Chemistry, vol.80, issue.11, pp.4055-4064, 2008.

J. J. Santana, J. González-guzmán, L. Fernández-mérida, S. González, and R. M. Souto, Visualization of local degradation processes in coated metals by means of scanning electrochemical microscopy in the redox competition mode, Electrochimica Acta, vol.55, issue.15, pp.4488-4494, 2010.

J. Will, A. Hoppe, F. A. Müller, C. T. Raya, J. M. Fernández et al., Bioactivation of biomorphous silicon carbide bone implants, Acta Biomaterialia, vol.6, issue.12, pp.4488-4494, 2010.

J. Y. Kim, H. S. Ahn, and A. J. Bard, Surface Interrogation Scanning Electrochemical Microscopy for a Photoelectrochemical Reaction: Water Oxidation on a Hematite Surface, Analytical Chemistry, vol.90, issue.5, pp.3045-3049, 2018.

A. Doménech-carbó, G. Cebrián-torrejón, L. De-miguel, V. Tordera, D. Rodrigues-furtado et al., dsDNA, ssDNA, G-quadruplex DNA, and nucleosomal DNA electrochemical screening using canthin-6-one alkaloid-modified electrodes, Electrochimica Acta, vol.115, pp.546-552, 2014.

A. Doménech-carbó, M. T. Doménech-carbó, M. L. Pérez, and M. Herrero-cortell, Detection of archaeological forgeries of Iberian lead plates using nanoelectrochemical techniques. The lot of fake plates from Bugarra (Spain), Forensic Science International, vol.247, pp.79-88, 2015.

A. Dragutinovic, S. Uitdehaag, and I. Kuiper, A reply to: The transferability of diatoms to clothing and the methods appropriate for their collection and analysis in forensic geoscience, Forensic Sci. Int. 241 (2014) 127?137, Forensic Science International, vol.247, p.e25, 2015.

J. Hui, M. Burgess, J. Zhang, and J. Rodríguez-lópez, Layer Number Dependence of Li+ Intercalation on Few-Layer Graphene and Electrochemical Imaging of Its Solid?Electrolyte Interphase Evolution, ACS Nano, vol.10, issue.4, pp.4248-4257, 2016.

K. C. Huang, J. Mater. Chem, vol.21, pp.10384-10389, 2011.

A. Sumboja, U. M. Tefashe, G. Wittstock, and P. S. Lee, Monitoring electroactive ions at manganese dioxide pseudocapacitive electrodes with scanning electrochemical microscope for supercapacitor electrodes, Journal of Power Sources, vol.207, pp.205-211, 2012.

M. Nebel, S. Grützke, N. Diab, A. Schulte, and W. Schuhmann, Microelectrochemical visualization of oxygen consumption of single living cells, Faraday Discussions, vol.164, p.19, 2013.

S. Gao, C. Dong, H. Luo, K. Xiao, X. Pan et al., Scanning electrochemical microscopy study on the electrochemical behavior of CrN film formed on 304 stainless steel by magnetron sputtering, Electrochimica Acta, vol.114, pp.233-241, 2013.

S. Thomas, I. S. Cole, Y. Gonzalez-garcia, M. Chen, M. Musameh et al., Oxygen consumption upon electrochemically polarised zinc, Journal of Applied Electrochemistry, vol.44, issue.6, pp.747-757, 2014.

I. Morkvenaite-vilkonciene, A. Ramanaviciene, P. Genys, and A. Ramanavicius, Evaluation of Enzymatic Kinetics of GOx-based Electrodes by Scanning Electrochemical Microscopy at Redox Competition Mode, Electroanalysis, vol.29, issue.6, pp.1532-1542, 2017.

F. Ivanauskas, I. Morkvenaite-vilkonciene, R. Astrauskas, A. Ramanavicius, and E. ,

. Acta, , vol.222, pp.347-354, 2016.

A. J. Wain, Imaging size effects on the electrocatalytic activity of gold nanoparticles using scanning electrochemical microscopy, Electrochimica Acta, vol.92, pp.383-391, 2013.

P. Sun and M. V. Mirkin, Kinetics of Electron-Transfer Reactions at Nanoelectrodes, Analytical Chemistry, vol.78, issue.18, pp.6526-6534, 2006.

B. B. Katemann, A. Schulte, and W. Schuhmann, Electroanalysis, vol.16, pp.60-65, 2004.

A. Tiwari, V. Singh, D. Mandal, and T. C. Nagaiah, Nitrogen containing carbon spheres as an efficient electrocatalyst for oxygen reduction: Microelectrochemical investigation and visualization, Journal of Materials Chemistry A, vol.5, issue.37, pp.20014-20023, 2017.

X. X. Chen, A. J. Botz, J. Masa, and W. Schuhmann, Characterisation of bifunctional electrocatalysts for oxygen reduction and evolution by means of SECM, Journal of Solid State Electrochemistry, vol.20, issue.4, pp.1019-1027, 2015.

R. Cornut and C. Lefrou, A unified new analytical approximation for negative feedback currents with a microdisk SECM tip, Journal of Electroanalytical Chemistry, vol.608, issue.1, pp.59-66, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00333788

M. V. Mirkin, S. Amemiya, and N. , Nanoelectrochemistry, pp.439-461, 2015.

K. Aoki and J. Osteryoung, Diffusion-controlled current at the stationary finite disk electrode, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.122, pp.19-35, 1981.

J. J. Salvador-pascual, S. Citalán-cigarroa, and O. Solorza-feria, Kinetics of oxygen reduction reaction on nanosized Pd electrocatalyst in acid media, Journal of Power Sources, vol.172, issue.1, pp.229-234, 2007.

T. N. Das, Saturation Concentration of Dissolved O2in Highly Acidic Aqueous Solutions of H2SO4, Industrial & Engineering Chemistry Research, vol.44, issue.6, pp.1660-1664, 2005.

Y. Shen, M. Träuble, and G. Wittstock, Detection of Hydrogen Peroxide Produced during Electrochemical Oxygen Reduction Using Scanning Electrochemical Microscopy, Analytical Chemistry, vol.80, issue.3, pp.750-759, 2008.

A. M. Gómez-marín, A. Boronat, and J. M. Feliu, Electrocatalytic oxidation and reduction of H2O2 on Au single crystals, Russian Journal of Electrochemistry, vol.53, issue.9, pp.1029-1041, 2017.

F. O. Laforge, J. Velmurugan, Y. Wang, and M. V. Mirkin, Nanoscale Imaging of Surface Topography and Reactivity with the Scanning Electrochemical Microscope, Analytical Chemistry, vol.81, issue.8, pp.3143-3150, 2009.

T. Yano, D. A. Tryk, K. Hashimoto, and A. Fujishima, Electrochemical Behavior of Highly Conductive Boron?Doped Diamond Electrodes for Oxygen Reduction in Alkaline Solution, Journal of The Electrochemical Society, vol.145, issue.6, pp.1870-1876, 1998.

C. Lefrou and R. Cornut, Analytical Expressions for Quantitative Scanning Electrochemical Microscopy (SECM), ChemPhysChem, vol.11, issue.3, pp.547-556, 2010.