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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Thomas Dumas 1, * Dominique Guillaumont 1 Philippe Moisy 1 David Shuh 2 Tolek Tyliszczak 2 Pier Lorenzo Solari 3 Christophe den Auwer 1
* Corresponding author
1 CEA-DES (ex-DEN) - CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire)
2 LBNL - Lawrence Berkeley National Laboratory [Berkeley]
3 SSOLEIL - Synchrotron SOLEIL
Abstract : In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs’ valence orbitals are probed by soft X-ray absorption measurements.
Keywords : f-element X-ray absorption spectroscopy
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https://hal-cea.archives-ouvertes.fr/cea-02983237
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Submitted on : Thursday, October 29, 2020 - 3:07:41 PM
Last modification on : Friday, July 2, 2021 - 3:41:50 AM

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CEA | DEN | SYNCHROTRON-SOLEIL | CNRS | INSTITUT-SCIENCES-LUMIERE

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Thomas Dumas, Dominique Guillaumont, Philippe Moisy, David Shuh, Tolek Tyliszczak, et al.. The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy. Chemical Communications, Royal Society of Chemistry, 2018, 54 (86), pp.12206-12209. ⟨10.1039/c8cc05176c⟩. ⟨cea-02983237⟩

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