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Journal Articles Chemical Communications Year : 2018

The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

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Abstract

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs’ valence orbitals are probed by soft X-ray absorption measurements.

Dates and versions

cea-02983237 , version 1 (29-10-2020)

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Thomas Dumas, Dominique Guillaumont, Philippe Moisy, David Shuh, Tolek Tyliszczak, et al.. The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy. Chemical Communications, 2018, 54 (86), pp.12206-12209. ⟨10.1039/c8cc05176c⟩. ⟨cea-02983237⟩
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