The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Thomas Dumas; Dominique Guillaumont; Philippe Moisy; David Shuh; Tolek Tyliszczak; Pier Lorenzo Solari; Christophe den Auwer

doi:10.1039/c8cc05176c

Journal articles

The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Thomas Dumas ^{1, *} Dominique Guillaumont ¹ Philippe Moisy ¹ David Shuh ² Tolek Tyliszczak ² Pier Lorenzo Solari ³ Christophe den Auwer ¹

* Corresponding author

1 CEA-DES (ex-DEN) - CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire)

2 LBNL - Lawrence Berkeley National Laboratory [Berkeley]

3 SSOLEIL - Synchrotron SOLEIL

Abstract : In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs’ valence orbitals are probed by soft X-ray absorption measurements.

Keywords : f-element X-ray absorption spectroscopy

Document type :

Journal articles

Domain :

Physics [physics] / Nuclear Theory [nucl-th]

Physics [physics] / Nuclear Experiment [nucl-ex]

Complete list of metadatas

https://hal-cea.archives-ouvertes.fr/cea-02983237
Contributor : Bibliothèque Cadarache <>
Submitted on : Thursday, October 29, 2020 - 3:07:41 PM
Last modification on : Friday, October 30, 2020 - 3:24:02 AM

The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Links full text

Identifiers

Collections

Relations

Citation

Export

Metrics

11

The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Links full text

Identifiers

Collections

Relations

Citation

Export

Share

Metrics

11