, The authors thank the beamline staff at the Advanced Photon Source, Chengjun Sun and Tianpin Wu for their assistance in the measurements. MR is thankful for financial support from the DFG via CRC 1073

, Office of Basic Energy Sciences under Contract

. Anders-filsøe-pedersen and E. L. Ifan, Stephens and Ib Chorkendorff for their assistance in carrying out the measurements at SLAC. The authors also thank Yu Katayama, Karthik Akkiraju and Yirui Zhang for their help with the DRIFTS measurements

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