Tailor‐Made Polydiacetylene Micelles for the Catalysis of 1,3‐Dipolar Cycloadditions in Water - Archive ouverte HAL Access content directly
Journal Articles Advanced Synthesis and Catalysis Year : 2020

Tailor‐Made Polydiacetylene Micelles for the Catalysis of 1,3‐Dipolar Cycloadditions in Water

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Abstract

A colloidal catalyst was developed by complexation of copper chloride in polydiacetylene micelles. The latter were designed to accommodate and stabilize copper salts, by providing a suitable liganded environment. Micelles were valorized as nanoreactors for the promotion of the Huisgen cycloaddition reaction in water thanks to their central hydrophobic core which permitted not only aqueous dispersion, but also concentration of the reagents at the vicinity of the catalyst. The system was found to be active on a variety of substrates and efficiently operated under sustainable conditions.
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Dates and versions

cea-02907952 , version 1 (28-07-2020)

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Cite

Ramar Arun Kumar, Dhanaji Jawale, Emmanuel Oheix, Valérie Geertsen, Edmond Gravel, et al.. Tailor‐Made Polydiacetylene Micelles for the Catalysis of 1,3‐Dipolar Cycloadditions in Water. Advanced Synthesis and Catalysis, 2020, 362 (20), pp.4425-4431. ⟨10.1002/adsc.202000795⟩. ⟨cea-02907952⟩
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