Skip to Main content Skip to Navigation
Journal articles

Tailor‐Made Polydiacetylene Micelles for the Catalysis of 1,3‐Dipolar Cycloadditions in Water

Abstract : A colloidal catalyst was developed by complexation of copper chloride in polydiacetylene micelles. The latter were designed to accommodate and stabilize copper salts, by providing a suitable liganded environment. Micelles were valorized as nanoreactors for the promotion of the Huisgen cycloaddition reaction in water thanks to their central hydrophobic core which permitted not only aqueous dispersion, but also concentration of the reagents at the vicinity of the catalyst. The system was found to be active on a variety of substrates and efficiently operated under sustainable conditions.
Complete list of metadatas

https://hal-cea.archives-ouvertes.fr/cea-02907952
Contributor : Serge Palacin <>
Submitted on : Tuesday, July 28, 2020 - 8:41:43 AM
Last modification on : Monday, October 26, 2020 - 7:16:35 AM

Identifiers

Citation

Ramar Arun Kumar, Dhanaji Jawale, Emmanuel Oheix, Valérie Geertsen, Edmond Gravel, et al.. Tailor‐Made Polydiacetylene Micelles for the Catalysis of 1,3‐Dipolar Cycloadditions in Water. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2020, 362 (20), pp.4425-4431. ⟨10.1002/adsc.202000795⟩. ⟨cea-02907952⟩

Share

Metrics

Record views

49