Low-pressure solubility of gases in liquid water, Chemical Reviews, vol.77, issue.2, pp.219-262, 1977. ,
Singlet and Other States with Extended Lifetimes, Encyclopedia of Magnetic Resonance, 2010. ,
Cryptophane-Xenon Complexes in Organic Solvents Observed through NMR Spectroscopy, The Journal of Physical Chemistry A, vol.112, issue.45, pp.11363-11372, 2008. ,
Quantitative chemical exchange saturation transfer with hyperpolarized nuclei (qHyper-CEST): Sensing xenon-host exchange dynamics and binding affinities by NMR, The Journal of Chemical Physics, vol.141, issue.19, p.194202, 2014. ,
Degeneracy in cryptophane-xenon complex formation in aqueous solution, Chemical Communications, vol.51, issue.9, pp.1721-1724, 2015. ,
Optical Pumping, Reviews of Modern Physics, vol.44, issue.2, pp.169-249, 1972. ,
Relaxation of spins due to field inhomogeneities in gaseous samples at low magnetic fields and low pressures, Physical Review A, vol.37, pp.2877-2885, 1988. ,
Spin-exchange optical pumping of noble-gas nuclei, Reviews of Modern Physics, vol.69, issue.2, pp.629-642, 1997. ,
Biosensing using laser-polarized xenon NMR/MRI, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.55, issue.1, pp.35-60, 2009. ,
Coatings for optical pumping cells and short-term storage of hyperpolarized xenon, Journal of Applied Physics, vol.87, issue.11, pp.8013-8017, 2000. ,
, , p.129
, Physics Letters A, vol.96, issue.4, pp.191-194, 1983.
Fast nuclear spin relaxation in hyperpolarized solid 129 ,
, Physical Review Letters, vol.88, p.147602, 2002.
Direct evidence of a magnetization transfer between laser-polarized xenon and protons of a cage-molecule in water, The European Physical Journal D -Atomic, Molecular, Optical and Plasma Physics, vol.12, issue.2, pp.289-296, 2000. ,
Hyperpolarized krypton-83 as a contrast agent for magnetic resonance imaging, Proceedings of the National Academy of Sciences, vol.102, issue.51, pp.18275-18279, 2005. ,
, Hyperpolarized 83 Kr and 129 Xe NMR Relaxation Measurements of Hydrated Surfaces: Implications for
, Materials Science and Pulmonary Diagnostics, vol.129, issue.6, pp.1784-1792, 2007.
, , p.83
, Kr MRI of lungs, Journal of Magnetic Resonance, vol.195, issue.2, pp.232-237, 2008.
Hyperpolarized 83 Kr magnetic resonance imaging of alveolar degradation in a rat model of emphysema, Journal of The Royal Society Interface, vol.12, issue.107, p.20150192, 2015. ,
Magnetic Resonance and Relaxation of Nuclei of Atomic Krypton in Liquid Solutions, Zeitschrift für Physikalische Chemie, vol.155, pp.55-68, 1987. ,
Cryogenics free production of hyperpolarized 129Xe and 83Kr for biomedical MRI applications, Journal of Magnetic Resonance, vol.237, pp.23-33, 2013. ,
, , p.129
, Proceedings of the National Academy of Sciences, vol.113, issue.12, pp.3164-3168, 2016.
Metastability exchange optical pumping of 3 He at high pressure and high magnetic field for medical applications, The European Physical Journal Special Topics, vol.144, issue.1, pp.255-263, 2007. ,
URL : https://hal.archives-ouvertes.fr/hal-02018581
A peristaltic compressor for hyperpolarized helium, European Radiology, vol.9, p.18, 1999. ,
Hyperpolarized 3 He gas production by metastability exchange optical pumping for magnetic resonance imaging, Optica Applicata, vol.35, pp.263-276, 2005. ,
, First results from Tyrex, the new polarized-3He filling station at ILL, vol.356, pp.103-108, 2005.
Magnetized boxes for housing polarized spins in homogeneous fields, Journal of Magnetic Resonance, vol.204, issue.1, pp.37-49, 2010. ,
NMR study of the dissolution of laser-polarized xenon, The European Physical Journal D -Atomic, Molecular and Optical Physics, vol.22, issue.1, pp.65-73, 2003. ,
, Optical hyperpolarization and NMR detection of 129 Xe on a microfluidic chip
Note: Spinexchange optical pumping in a van, Review of Scientific Instruments, vol.87, issue.1, p.16105, 2016. ,
A magnetic tunnel to shelter hyperpolarized fluids, Review of Scientific Instruments, vol.86, issue.2, p.24101, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01122001
, , p.129
, Applied Magnetic Resonance, vol.44, issue.1-2, pp.65-80, 2013.
Transport of hyperpolarized samples in dissolution-DNP experiments, Physical Chemistry Chemical Physics, vol.21, issue.25, pp.13696-13705, 2019. ,
URL : https://hal.archives-ouvertes.fr/hal-02183739
A dedicated spectrometer for dissolution DNP NMR spectroscopy, Physical Chemistry Chemical Physics, vol.12, issue.22, p.5883, 2010. ,
Scalable dissolution-dynamic nuclear polarization with rapid transfer of a polarized solid, Nature Communications, vol.10, issue.1, 2019. ,
Parahydrogen induced polarization, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.31, issue.4, pp.293-315, 1997. ,
The role of level anticrossings in nuclear spin hyperpolarization, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.81, pp.1-36, 2014. ,
Chemical kinetics and spin dynamics of the formation of hyperpolarization, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.114, pp.33-70, 2019. ,
LIGHT-SABRE enables efficient in-magnet catalytic hyperpolarization, Journal of Magnetic Resonance, vol.248, pp.23-26, 2014. ,
RF-SABRE: A Way to Continuous Spin Hyperpolarization at High Magnetic Fields, The Journal of Physical Chemistry B, vol.119, issue.43, pp.13619-13629, 2015. ,
Chemical Exchange Reaction Effect on Polarization Transfer Efficiency in SLIC-SABRE, The Journal of Physical Chemistry A, vol.122, issue.46, pp.9107-9114, 2018. ,
Parahydrogen based NMR hyperpolarisation goes micro: an alveolus for small molecule chemosensing, Lab on a Chip, vol.19, issue.3, pp.503-512, 2019. ,
Magnetic resonance imaging of dissolved hyperpolarized 129 Xeusing a membrane-based continuous flow system, Journal of Magnetic Resonance, vol.201, issue.1, pp.93-99, 2009. ,
, NMR and MRI of Blood-Dissolved Hyperpolarized Xe-129 in Different Hollow-Fiber Membranes, vol.12, pp.2941-2947, 2011.
Optimized Continuous Application of Hyperpolarized Xenon to Liquids, The Journal of Physical Chemistry A, vol.122, pp.9359-9369, 2018. ,
Continuous hyperpolarization with parahydrogen in a membrane reactor, Journal of Magnetic Resonance, vol.291, pp.8-13, 2018. ,
Continuous 1 H and 13 C Signal Enhancement in NMR Spectroscopy and MRI Using Parahydrogen and Hollow-Fiber Membranes, Angewandte Chemie International Edition, vol.49, issue.45, pp.8358-8362, 2010. ,
Continuously Infusing Hyperpolarized 129 Xe into Flowing Aqueous Solutions Using Hydrophobic Gas Exchange Membranes, The Journal of Physical Chemistry B, vol.113, issue.37, pp.12489-12499, 2009. ,
In Vivo MR Imaging of Pulmonary Perfusion and Gas Exchange in Rats via Continuous Extracorporeal, p.129 ,
, PLoS ONE, vol.7, issue.2, p.31306, 2012.
Berthault, 3d-printed system optimizing dissolution of hyperpolarized gaseous species for micro-sized NMR, Lab on a Chip, vol.15, issue.9, pp.2049-2054, 2015. ,
Enhancing NMR of Nonrelaxing Species Using a Controlled Flow Motion and a Miniaturized Circuit, Analytical Chemistry, vol.89, issue.5, pp.2995-3000, 2017. ,
URL : https://hal.archives-ouvertes.fr/cea-01449824
Inductive Coupling and Flow for Increased NMR Sensitivity, Analytical Chemistry, vol.90, issue.19, pp.11169-11173, 2018. ,
URL : https://hal.archives-ouvertes.fr/cea-01872249
The 13 C hyperpolarized pyruvate generated by ParaHydrogen detects the response of the heart to altered metabolism in real time, Scientific Reports, vol.8, issue.1, 2018. ,
, Angewandte Chemie International Edition, vol.57, issue.35, pp.11140-11162, 2018.
Heterogeneous Solution NMR Signal Amplification by Reversible Exchange, Angewandte Chemie International Edition, vol.53, issue.29, pp.7495-7498, 2014. ,
Nanoscale Catalysts for NMR Signal Enhancement by Reversible Exchange, The Journal of Physical Chemistry C, vol.119, issue.13, pp.7525-7533, 2015. ,
,
, Heterogeneous Microtesla SABRE, p.15
, Angewandte Chemie International Edition, vol.56, issue.35, p.10433, 2017.
, Tweezers for Parahydrogen: A Metal-Free Probe of Nonequilibrium Nuclear Spin States of H
, Journal of the American Chemical Society, vol.136, issue.2, pp.598-601, 2014.
, , p.15
, N Nuclear Spin Hyperpolarization in Metal-Free Activation of Parahydrogen by Molecular Tweezers, The Journal of Physical Chemistry Letters, vol.9, issue.4, pp.903-907, 2018.
Achieving High Levels of NMR-Hyperpolarization in Aqueous Media With Minimal Catalyst Contamination Using SABRE, Chemistry -A European Journal, vol.23, issue.44, pp.10491-10495, 2017. ,
Rapid Catalyst Capture Enables Metal-Free para -Hydrogen-Based Hyperpolarized Contrast Agents, The Journal of Physical Chemistry Letters, vol.9, issue.11, pp.2721-2724, 2018. ,
Scavenging Free Radicals To Preserve Enhancement and Extend Relaxation Times in NMR using Dynamic Nuclear Polarization, Angewandte Chemie International Edition, vol.49, issue.35, pp.6182-6185, 2010. ,
The effect of glassing solvent deuteration and Gd 3+ doping on 13 ,
, C DNP at 5 T, RSC Advances, vol.6, issue.45, pp.38855-38860, 2016.
Nuclear spin hyperpolarization with ansa-aminoboranes: a metal-free perspective for parahydrogen-induced polarization, Physical Chemistry Chemical Physics, vol.18, issue.40, pp.27784-27795, 2016. ,
NMR Spectroscopy Unchained: Attaining the Highest Signal Enhancements in Dissolution Dynamic Nuclear Polarization, The Journal of Physical Chemistry Letters, vol.9, issue.18, pp.5481-5489, 2018. ,
Transportable hyperpolarized metabolites, Nature Communications, vol.8, issue.1, 2017. ,
URL : https://hal.archives-ouvertes.fr/hal-01577303
Photoinduced Nonpersistent Radicals as Polarizing Agents for X-Nuclei Dissolution Dynamic Nuclear Polarization, The Journal of Physical Chemistry C, vol.119, issue.39, pp.22632-22639, 2015. ,
Thermal annihilation of photo-induced radicals following dynamic nuclear polarization to produce transportable frozen hyperpolarized 13 C-substrates, Nature Communications, vol.8, issue.1 ,
, Photogenerated Radical in Phenylglyoxylic Acid for in Vivo Hyperpolarized 13 C
URL : https://hal.archives-ouvertes.fr/hal-02091880
, MR with Photosensitive Metabolic Substrates, vol.140, pp.14455-14463, 2018.
Flexible automation with compact NMR spectroscopy for continuous production of pharmaceuticals, Analytical and Bioanalytical Chemistry, vol.411, issue.14, pp.3037-3046, 2019. ,
Rapid sample injection for hyperpolarized NMR spectroscopy, Physical Chemistry Chemical Physics, vol.12, issue.22, p.5766, 2010. ,
Industrial on-line analysis by nuclear magnetic resonance spectroscopy, 2002. ,
Integrated Microreactors for Reaction Automation: New Approaches to Reaction Development, Annual Review of Analytical Chemistry, vol.3, issue.1, pp.19-42, 2010. ,
A simple way to properly invert intense nuclear magnetization: application to laser-polarized xenon, Chemical Physics Letters, vol.314, issue.1-2, pp.52-56, 1999. ,
, , p.129
, Xe NMR spectra of large magnetization created by dissolved laser-polarized xenon, Comptes Rendus Chimie, vol.11, issue.4-5, pp.553-559, 2008.
Observation of Noise-Triggered Chaotic Emissions in an NMR-Maser, ChemPhysChem, vol.9, issue.10, pp.1395-1401, 2008. ,
Sensitivity and Multiplexing Capabilities of MRI Based on Polarized 129 ,
, Journal of the American Chemical Society, vol.130, issue.49, pp.16456-16457, 2008.
NMR Trace Analysis by Continuous Hyperpolarization at High Magnetic Field, Angewandte Chemie International Edition, vol.54, issue.48, pp.14527-14530, 2015. ,
The acquisition of multidimensional NMR spectra within a single scan, Proceedings of the National Academy of Sciences, vol.99, issue.25, pp.15858-15862, 2002. ,
Spatial encoding and spatial selection methods in high-resolution NMR spectroscopy, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.109, pp.101-134, 2018. ,
Ultrafast two-dimensional nuclear magnetic resonance spectroscopy of hyperpolarized solutions, Nature Physics, vol.3, issue.6, pp.415-419, 2007. ,
Conversion of parahydrogen induced longitudinal two-spin order to evenly distributed single spin polarisation by optimal control pulse sequences, The Journal of Chemical Physics, vol.136, issue.9, p.94201, 2012. ,
,
Utilization of SABRE-Derived Hyperpolarization To Detect Low-Concentration Analytes via 1D and 2D NMR Methods, Journal of the American Chemical Society, vol.134, issue.31, pp.12904-12907, 2012. ,
Single-Scan Multidimensional NMR Analysis of Mixtures at Sub-Millimolar Concentrations by using SABRE Hyperpolarization, ChemPhysChem, vol.16, issue.16, pp.3413-3417, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01228706
, Single-Scan 13 C Diffusion-Ordered
, NMR Spectroscopy of DNP-Hyperpolarised Substrates, vol.23, issue.66, pp.16722-16727, 2017.
Single-Scan Diffusion-Ordered NMR Spectroscopy of SABRE-Hyperpolarized Mixtures, ChemPhysChem, vol.20, issue.3, pp.392-398, 2019. ,
URL : https://hal.archives-ouvertes.fr/cea-01947738
Ultrafast multidimensional Laplace NMR for a rapid and sensitive chemical analysis, Nature Communications, vol.6, issue.1, 2015. ,
Chemical exchange saturation transfer imaging and spectroscopy, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.48, issue.2-3, pp.109-136, 2006. ,
From basic principles to applications, challenges and opportunities, frontiers of In Vivo and Materials MRI Research, vol.229, pp.155-172, 2013. ,
Molecular Imaging Using a Targeted Magnetic Resonance Hyperpolarized Biosensor, Science, vol.314, issue.5798, pp.446-449, 2006. ,
,
Smart Detection of Toxic Metal Ions, Pb 2+ and Cd 2+ , Using a 129 Xe NMR-Based Sensor, Analytical Chemistry, vol.86, issue.3, pp.1783-1788, 2014. ,
URL : https://hal.archives-ouvertes.fr/hal-01117441
Ultrafast Scanning of Exchangeable Sites by NMR Spectroscopy, Angewandte Chemie International Edition, vol.52, issue.32, pp.8281-8284, 2013. ,
Ultrafast Z-Spectroscopy for 129 Xe NMR-Based Sensors, The Journal of Physical Chemistry Letters, vol.4, issue.23, pp.4172-4176, 2013. ,
URL : https://hal.archives-ouvertes.fr/hal-01896791
Fast Gradient-Encoded CEST Spectroscopy of Hyperpolarized Xenon, ChemPhysChem, vol.15, issue.2, pp.261-264, 2014. ,
, Journal of Magnetic Resonance, vol.243, pp.47-53, 2014.
,
Indirect Detection of Short-Lived Hydride Intermediates of Iridium N-Heterocyclic Carbene Complexes via Chemical Exchange Saturation Transfer Spectroscopy, The Journal of Physical Chemistry C, vol.123, issue.26, pp.16288-16293, 2019. ,
The upcoming 3d-printing revolution in microfluidics, Lab Chip, vol.16, pp.1720-1742, 2016. ,
, 3d printed microfluidic devices: enablers and barriers, vol.16, pp.1993-2013, 2016.
Evaluation of polyethylene glycol diacrylate-polycaprolactone scaffolds for tissue engineering applications, Journal of Functional Biomaterials, vol.8, issue.3 ,
Recent advances in biomaterials for 3d printing and tissue engineering, Journal of Functional Biomaterials, vol.9, issue.1 ,
Recent advances in photo-crosslinkable hydrogels for biomedical applications, BioTechniques, vol.66, issue.1, pp.40-53, 2019. ,
, , p.129
, Xe NMR signature of living biological cells, NMR in Biomedicine, vol.24, issue.10, pp.1264-1269, 2011.
Hyperpolarized 129 Xe NMR as a probe for blood oxygenation, Magnetic Resonance in Medicine, vol.43, issue.4, pp.491-496, 2000. ,
Biosensing and Study of Biological Cells using Hyperpolarized 129Xe, Hyperpolarized Xenon-129 Magnetic Resonance, vol.14, pp.261-271, 2015. ,
URL : https://hal.archives-ouvertes.fr/cea-01257658
Discovery of Intermediates of lacZ ?-Galactosidase Catalyzed Hydrolysis Using dDNP NMR, Journal of the American Chemical Society, vol.140, issue.8, pp.3030-3034, 2018. ,
, Real Time Nuclear Magnetic Resonance Detection of Fumarase Activity using Parahydrogen-Hyperpolarized
NMR analysis on microfluidic devices by remote detection, Analytical Chemistry, vol.77, issue.24, pp.8109-8114, 2005. ,
Pushing nuclear magnetic resonance sensitivity limits with microfluidics and photo-chemically induced dynamic nuclear polarization, Nature Communications, vol.9, issue.1 ,
NMR Imaging of Catalytic Hydrogenation in Microreactors with the Use of parahydrogen, Science, vol.319, issue.5862, pp.442-445, 2008. ,
, Gas-Flow Imaging Utilizing Parahydrogen-Induced Polarization and Remote-Detection NMR, vol.49, pp.8363-8366, 2010.
High-Resolution Nuclear Magnetic Resonance Spectroscopy with Picomole Sensitivity by Hyperpolarization on a Chip, Journal of the American Chemical Society, vol.141, issue.25, pp.9955-9963, 2019. ,
Using para hydrogen to hyperpolarize amines, amides, carboxylic acids, alcohols, phosphates, and carbonates, Science Advances, vol.4, issue.1, p.6250, 2018. ,
Long live the singlet state!, Journal of Magnetic Resonance, vol.306, pp.69-74, 2019. ,
Direct Enhancement of Nuclear Singlet Order by Dynamic Nuclear Polarization, Journal of the American Chemical Society, vol.134, issue.18, pp.7668-7671, 2012. ,
Hyperpolarized singlet lifetimes of pyruvate in human blood and in the mouse: Hyperpolarized Singlet Lifetimes of Pyruvate In Vivo, NMR in Biomedicine, vol.26, issue.12, pp.1696-1704, 2013. ,
Hyperpolarising Pyruvate through Signal Amplification by Reversible Exchange (SABRE), Angewandte Chemie International Edition, vol.58, issue.30, pp.10271-10275, 2019. ,
High-resolution magnetic resonance spectroscopy using a solid-state spin sensor, Nature, vol.555, issue.7696, pp.351-354, 2018. ,