On the O-rich domain of the U-Am-O phase diagram
Abstract
Uranium–Americium oxides U$_{1−y}$Am$_y$O$_{2±x}$ are promising candidates as possible transmutation targets for next generation nuclear reactors. In the context of a comprehensive investigation of their thermodynamic and thermal properties, the behaviour in oxidizing conditions is here studied. In a recent work, the behaviour in air of stoichiometric and sub-stoichiometric U$_{1−y}$Am$_y$O$_{2±x}$ compounds, with various Am content, was investigated by high-temperature X-ray Diffraction. Herein, the hyper-stoichiometric oxides obtained from that study are investigated by X-ray Absorption Spectroscopy. The new data, together with the previous XRD results, allow determining the exact compositions of the samples and hence obtaining phase diagram points in the O-rich domain of the U-Am-O system. Indeed, five phase diagram points at 1473 K are obtained: two tie-lines in the M$_4$O${9-}$M$_3$O$_8$ domain, for Am/(Am + U) = 0.10 and 0.15, one tie line in the MO$_{2+x-}$M$_3$O$_8$ domain, for Am/(Am + U) = 0.28, and two points in the single phase MO$_{2±x}$ domain, for higher americium concentration. From these data, it is also concluded that trivalent americium has a small solubility in the M$_4$O$_9$ and M$_3$O$_8$ phases.
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