Peculiar Behavior of (U,Am)O 2−δ Compounds for High Americium Contents Evidenced by XRD, XAS, and Raman Spectroscopy

Florent Lebreton (1) , Denis Horlait , Richard L Caraballo (2) , P.M. Martin , Andreas Scheinost (3) , André Rossberg (4) , Christophe Jégou (2) , Thibaud Delahaye (5)

1 DMRC - Département de recherche sur les procédés pour la mine et le recyclage du combustible
2 SECM - Service d'Etudes du Comportement des Matériaux de Conditionnement
3 HZDR - Helmholtz-Zentrum Dresden-Rossendorf
4 ESRF - European Synchrotron Radiation Facility
5 CEA-DES (ex-DEN) - CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire)

Domains: Cristallography; Material chemistry; Materials Science [cond-mat.mtrl-sci]

Florent Lebreton, Denis Horlait, Richard L Caraballo, P.M. Martin, Andreas Scheinost, et al.. Peculiar Behavior of (U,Am)O 2−δ Compounds for High Americium Contents Evidenced by XRD, XAS, and Raman Spectroscopy. Inorganic Chemistry, 2015, 54 (20), pp.9749-9760. ⟨10.1021/acs.inorgchem.5b01357⟩. ⟨cea-02528978⟩