 |
Journal articles
Developing Remote Metal Binding Sites in Heteropolymolybdates
Abstract : Anderson‐type polyoxomolybdates [MMo6O18{(OCH2)3CNH2}2]3− (M = MnIII, FeIII) were prepared and structurally characterized. The tris(alkoxo) ligands are bound to the central heteroatom via their oxygen atoms. The corresponding compounds with M = NiII or ZnII are not accessible since these cations have a preference for the amino functionality. The pendant amino groups of the manganese‐containing derivative react with pyridinecarbaldehydes to give the corresponding imines. This provides new mono‐ and bidentate binding sites for metal cations.
Cited literature [62 references]
https://hal-cea.archives-ouvertes.fr/cea-02528430
Contributor : Pierre R. Marcoux Connect in order to contact the contributor
Submitted on : Wednesday, April 1, 2020 - 6:22:45 PM
Last modification on : Tuesday, January 25, 2022 - 8:18:01 AM
Contributor : Pierre R. Marcoux Connect in order to contact the contributor
Submitted on : Wednesday, April 1, 2020 - 6:22:45 PM
Last modification on : Tuesday, January 25, 2022 - 8:18:01 AM
File
B Hazenknopf et al.pdf
Files produced by the author(s)