, Fe(III)-enriched nickel chromite, Ni(Fe,Cr) 2 O 4 outer-layer (dispersed crystallites (<50nm)): Fe(III) hematite ?-Fe, vol.2
, Inner-layer destruction: low density distribution of cavity (~(0.2-5) µm 2 , depth (1-1.5µm), ~(1-5)x10 -9
, Oxide Growth on 316L at ~(300°C,90 bar): e-flux effect Synthesis of Structural & Chemical Analysis, p.3
, Oxide Growth at ~(300°C,90 bar) 316L(e-)/water(PWR,e-) interface (no flow rate) Inner oxide: Ni(Fe,Cr)
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, Irradiation defects & Radiolysis Species Summary inner oxide destruction and dissolution e-Flux on: composition change Outer oxide (crystallites): ?-Fe, vol.2
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, Flux on: release rate increase rFe>>rNi> rCr (r: ratio of release rate
, , 2013.
, Why Fe(III) enrichment and loss of Fe
, It seems to be consistent with the statement * that Fenton reactions Fe n + with radolytic H 2 O 2 : peroxide favoring high ion valence state (*Barbusinki, 2009.