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Journal articles
Visible-Light-Driven Reduction of CO$_2$ to CO and Its Subsequent Valorization in Carbonylation Chemistry and $^{13}$C Isotope Labeling
Abstract : A convenient and safe approach in valorizing carbon monoxide (CO) produced from the photocatalytic reduction of carbon dioxide (CO$_2$) has been investigated. Visible light was used to drive an optimized photocatalytic reduction using a ruthenium trisbipyridine complex as a sensitizer and a rhenium bipyridyl carbonyl complex as a catalyst to perform an efficient reduction of CO2 to CO, which was then simultaneously utilized in a palladium-catalyzed aminocarbonylation reaction at room temperature. This approach provides a safe handling of the produced CO which also opens the way for a more efficient application of $^{13}$C-isotope and $^{14}$C-radioisotope labeled CO$_2$ in pharmaceutically-relevant drug labeling.
Cited literature [53 references]
https://hal-cea.archives-ouvertes.fr/cea-02503934
Contributor : Davide Audisio <>
Submitted on : Tuesday, March 10, 2020 - 12:58:12 PM
Last modification on : Wednesday, September 16, 2020 - 5:16:29 PM
Long-term archiving on: : Thursday, June 11, 2020 - 4:13:31 PM
Contributor : Davide Audisio <>
Submitted on : Tuesday, March 10, 2020 - 12:58:12 PM
Last modification on : Wednesday, September 16, 2020 - 5:16:29 PM
Long-term archiving on: : Thursday, June 11, 2020 - 4:13:31 PM
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two chamber_rev23.pdf
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