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Versatile Access to N-Functionalized Iminosydnones by Carbonylimidazolium Activation

Margaux Riomet 1 Karine Porte 1 Léa Madegard 1 Pierre Thuéry 2 Davide Audisio 3 Frédéric Taran 1, * 
* Corresponding author
2 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
3 LMC - Laboratoire de Marquage au Carbone 14
SCBM - Service de Chimie Bio-Organique et de Marquage : DRF/JOLIOT
Abstract : A new methodology for N-exocyclic functionalization of iminosydnones was developed involving the addition of a large variety of nucleophiles on carbonyl-imidazolium activated iminosydnones. This practical and highly versatile method pro-vided access to new classes of iminosydnones and opened a straight-forward synthetic route to prepare iminosydnone-based prodrugs.
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Submitted on : Monday, March 9, 2020 - 11:42:08 PM
Last modification on : Sunday, June 26, 2022 - 2:47:46 AM


  • HAL Id : cea-02503416, version 1


Margaux Riomet, Karine Porte, Léa Madegard, Pierre Thuéry, Davide Audisio, et al.. Versatile Access to N-Functionalized Iminosydnones by Carbonylimidazolium Activation. Organic Letters, American Chemical Society, In press. ⟨cea-02503416⟩



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