Complexation of actinides by branched N-macrocycle DOTA - Archive ouverte HAL Access content directly
Conference Papers Year : 2015

Complexation of actinides by branched N-macrocycle DOTA

(1) , (1) , (1) , (1) , (1) , (1) , (2) , (2) , (3) , (4) , (5) , (6)
1
2
3
4
5
6

Abstract

This study shows the differences of behavior for the actinide (An) cations with their valence and its size in a given series versus the more or less hard donor atoms, such as oxygen and nitrogen. Plutonium(III) and americium(III) were chosen to represent the An(III) series, and for the An(+IV) series, uranium, neptunium and plutonium were selected. The DOTA ligand, which is very well known for the cations in solution other than the actinides, was chosen because it has the two donor atoms: oxygen and nitrogen.
Fichier principal
Vignette du fichier
201500000560.pdf (152.71 Ko) Télécharger le fichier
Origin : Files produced by the author(s)
Loading...

Dates and versions

cea-02489496 , version 1 (24-02-2020)

Identifiers

  • HAL Id : cea-02489496 , version 1

Cite

M. Audras, L. Berthon-Nigond, C. Berthon, N. Zorz, D. Guillaumont, et al.. Complexation of actinides by branched N-macrocycle DOTA. SCF Congress 2015 - Congrès de la société Chimique de France 2015, Jul 2015, Lille, France. ⟨cea-02489496⟩
17 View
34 Download

Share

Gmail Facebook Twitter LinkedIn More