Skip to Main content Skip to Navigation
Journal articles

Contribution of zeolite-seeded experiments to the understanding of glass resumption of alteration

Abstract : Understanding the origin and the consequences of glass alteration regimes is necessary for the prediction of nuclear glass durability. The so-called “stage 3” or “resumption of alteration regime” of glasses used to sequester nuclear waste by vitrification, is characterized by a sudden acceleration of glass alteration rate arising from the precipitation of secondary minerals, mainly zeolites. To study this process, a promising approach is developed, based on seeding by synthesized zeolite seeds. This study quantitatively links the alteration of a six-oxide reference borosilicate glass (ISG) and the precipitation of zeolites that affects concentrations of key species—in particular aluminum—and thus the glass dissolution rate. The characterization of stage 3—easier at alkaline pH—can now be extended to pH conditions more representative of those found in a geological repository thanks to seeding that reduces, or even eliminates, the latency period preceding a resumption of glass alteration. The resumption occurrence and glass dissolution rate are related with temperature and pH. This study shows that the detrimental effect of zeolite precipitation decreases with decreasing pH and temperature, until it is no longer detectable at a pH around 9 imposed by the dissolution of the ISG glass. Even for both high temperature and high pH, the resumption rate is lower than the initial alteration rate, which remains the fastest kinetic regime
Complete list of metadata

Cited literature [57 references]  Display  Hide  Download
Contributor : amplexor amplexor Connect in order to contact the contributor
Submitted on : Thursday, December 19, 2019 - 9:46:06 AM
Last modification on : Tuesday, June 22, 2021 - 9:28:02 AM


Publisher files allowed on an open archive





M. Fournier, S. Gin, P. Frugier, S. Depierre. Contribution of zeolite-seeded experiments to the understanding of glass resumption of alteration. npj Materials Degradation, Nature Research 2017, 1, pp.17. ⟨10.1038/s41529-017-0018-x⟩. ⟨cea-02418695⟩



Record views


Files downloads