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Journal articles
Mn 0.7 Fe 2.3 O 4 Nanoplatelets Embedded in BaTiO 3 Perovskite Thin Films for Multifunctional Composite Barriers
Phuong-Linh Nguyen
1
Brice Sarpi
2
Federico Petronio
2, 1
Cristian Mocuta
2
Philippe Ohresser
2
Dana Stanescu
1
Jean-Baptiste Moussy
1
Alina Vlad
2
Andrea Resta
2
Edwige Otero
2
Rachid Belkhou
2
Jocelyne Leroy
3
Nathalie Jedrecy
4
Hélène Magnan
1
Antoine Barbier
1
1
LNO - Laboratoire Nano-Magnétisme et Oxydes
SPEC - UMR3680 - Service de physique de l'état condensé, IRAMIS - Institut Rayonnement Matière de Saclay
3
LICSEN - Laboratoire Innovation en Chimie des Surfaces et NanoSciences
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Phuong-Linh Nguyen 1
Author
Brice B Sarpi 2
Author
Federico Petronio 2, 1
Author IdHAL : federico-petronio ORCID : https://orcid.org/0000-0002-1273-9641
Cristian Mocuta 2
Author
Philippe Ohresser 2
Author
Dana Stanescu 1
Author IdHAL : dana-stanescu ORCID : https://orcid.org/0000-0003-1881-8495
Jean-Baptiste Moussy 1
Author
Alina Vlad 2
Author
Nathalie Jedrecy 4
Author IdHAL : nathalie-jedrecy
Hélène Magnan 1
Author
Antoine Barbier 1
Author IdHAL : antoine-barbier ORCID : https://orcid.org/0000-0002-1032-299X
1
LNO - Laboratoire Nano-Magnétisme et Oxydes (France)
- SPEC - UMR3680 - Service de physique de l'état condensé (SPEC - UMR3680 CEA-CNRS
(ex-URA 2464),
CEA/Saclay,
Orme des Merisiers,
F-91191 GIF SUR YVETTE CEDEX - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- CNRS - Centre National de la Recherche Scientifique : UMR3680 (France)
- IRAMIS - Institut Rayonnement Matière de Saclay (91191 Gif-sur-Yvette, France - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
2
SSOLEIL - Synchrotron SOLEIL (L'Orme des Merisiers Saint-Aubin - BP 48 91192 GIF-sur-YVETTE CEDEX - France)
- CNRS - Centre National de la Recherche Scientifique : UR1 (France)
3
LICSEN - Laboratoire Innovation en Chimie des Surfaces et NanoSciences (LICSEN, NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91190 Gif sur Yvette - France)
- NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M) (NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91190 Gif sur Yvette - France)
- IRAMIS - Institut Rayonnement Matière de Saclay : DRF/IRAMIS (91191 Gif-sur-Yvette, France - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- CNRS - Centre National de la Recherche Scientifique : UMR3685 (France)
- IRAMIS - Institut Rayonnement Matière de Saclay : DRF/IRAMIS (91191 Gif-sur-Yvette, France - France)
4
INSP - Institut des Nanosciences de Paris (Université Pierre et Marie Curie Case 840 4 place Jussieu 75252 Paris Cedex 05 - France)
- UPMC - Université Pierre et Marie Curie - Paris 6 (4 place Jussieu - 75005 Paris - France)
- CNRS - Centre National de la Recherche Scientifique : UMR7588 (France)
Abstract : Multifunctional materials having the ability to respond to various external fields are tremendously sought; not only for their potential use as sensing components for devices, but also because they provide an elegant way to optimize materials usage. However, multifunctional single-phase materials are scarce and one approach to overcome this problem is to build artificial compounds combining different properties. This is a challenging materials science task, especially when two-dimensional structures are considered. In this paper, we report on the successful realization of multifunctional systems consisting of ferrimagnetic Mn0.7Fe2.3O4 spinel platelets, of controlled sizes and nanometric thicknesses, embedded in an epitaxial ferroelectric BaTiO3 perovskite thin film. The embedded platelets experience a much higher isostatic strain than that obtained for single layers. We successfully achieved nanometer-thick composite layers, with identical composition, having either in plane or out of plane electric polarization orientations. The optimal samples combine several functionalities: (i) the magnetoelectric nature of the full oxide artificial structures is confirmed; (ii) semiconducting diode behaviors are obtained when contacted with a metal electrode and (iii) marked (8 fold) electro-resistance transport properties with respect to the electric polarization orientation are revealed. The embedded platelets configuration enhances significantly interface and two-dimensional effects and is thus believed of high interest to realize functional device structures.
Document type :
Journal articles
Domain :
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https://hal-cea.archives-ouvertes.fr/cea-02403670
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Tuesday, December 10, 2019 - 10:46:39 PM
Last modification on : Thursday, July 1, 2021 - 4:44:17 PM
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Tuesday, December 10, 2019 - 10:46:39 PM
Last modification on : Thursday, July 1, 2021 - 4:44:17 PM
Identifiers
- HAL Id : cea-02403670, version 1
- DOI : 10.1021/acsanm.9b01970
Collections
CEA | INSP | ALLINSP | PUBNIMBE | IRAMIS-NIMBE | IRAMIS-SPEC | CEA-UPSAY | INC-CNRS | SYNCHROTRON-SOLEIL | SU-SCIENCES | CNRS | SORBONNE-UNIVERSITE | INSP-E5 | ANR | IRAMIS | GS-CHIMIE | GS-ENGINEERING | INSTITUT-SCIENCES-LUMIERE
Citation
Phuong-Linh Nguyen, Brice Sarpi, Federico Petronio, Cristian Mocuta, Philippe Ohresser, et al.. Mn 0.7 Fe 2.3 O 4 Nanoplatelets Embedded in BaTiO 3 Perovskite Thin Films for Multifunctional Composite Barriers. ACS Applied Nano Materials, American Chemical Society, 2019, 3, pp.327-341. ⟨10.1021/acsanm.9b01970⟩. ⟨cea-02403670⟩
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