Inner and outer sphere plutonium(IV) coordination with amide and carbamide ligands

D. Guillaumont (1) , E Acher (1) , Clemence Berger (1) , T. Dirks (1) , N. Boubals (1) , Thomas Dumas (2, 1) , Christelle Tamain (1) , Cecile Marie (2, 1) , Laurence Berthon (2, 1)

1 CEA-DES (ex-DEN) - CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire)
2 DMRC - Département de recherche sur les procédés pour la mine et le recyclage du combustible

In the present work, we have combined spectroscopic and computational methods to elucidate the structures of plutonium(IV) ions with dialkyl monoamide and tetraalkyl-carbamide ligands in the solid state and in solution.

Keywords: monoamide; carbamide; plutonium

Domains: Nuclear Experiment [nucl-ex]; Nuclear Theory [nucl-th]

D. Guillaumont, E Acher, Clemence Berger, T. Dirks, N. Boubals, et al.. Inner and outer sphere plutonium(IV) coordination with amide and carbamide ligands. Plutonium FuturesThe Science 2018, Sep 2018, San Diego, United States. ⟨cea-02400198⟩