Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. I. Theoretical considerations, American Journal of Science, vol.282, pp.237-285, 1982. ,
, Mécanismes et vitesses de dissolution initiales du verre de référence R7T7 inactif dans l'eau à 50°C, pp.93-117, 1993.
Aqueous corrosion of French R7T7 nuclear waste glass: selective then congruent dissolution by pH increase, Comptes Rendus de l'Académie des Sciences -Series II, vol.313, pp.407-412, 1991. ,
Hydrolysis of R7T7 Nuclear Waste Glass in Dilute Media: Mechanisms and Rate as a function of pH, Materials Research Society Symposium Proceedings, vol.212, pp.57-64, 1990. ,
Influence of calcium on sodium aluminosilicate glass leaching behaviour, Physics and Chemistry of Glasses, vol.42, issue.4-5, pp.279-286, 2001. ,
, Standard Test Method for Setermining Chemical Durability of Nuclear, Hazardeous, and Mixed Waste Glasses and Multiphase Glass Ceramics: The Product Consistency Test (PCT), 2008.
Diffusion processes in surface layers of glass, Physics and Chemistry of Glasses, vol.8, issue.4, pp.140-144, 1967. ,
A kinetic model for borosilicate glass dissolution affinity of a surface alteration layer, Materials Research Society Symposium Proceedings, vol.176, pp.209-216, 1989. ,
Molecular mechanisms for corrosion of silica and silicate glasses, Journal of Non-Crystalline Solids, vol.179, pp.300-308, 1994. ,
Insight into silicate-glass corrosion mechanisms, Nature Materials, vol.7, issue.12, pp.978-983, 2008. ,
Why do certain glasses with a high dissolution rate undergo a low degree of corrosion?, Journal of Physical Chemistry C, vol.115, issue.13, pp.5846-5855, 2011. ,
X-ray absorption spectroscopic studies of silicate glasses and minerals, Physics and Chemistry of Minerals, vol.15, issue.1, pp.19-29, 1987. ,
Experimental study of the dissolution rates of a simulated borosilicate waste glass as a function of pH and temperature. Abstracts of Papers of the, p.234, 2007. ,
Performance assessment of radioactive-waste repositories, Science, vol.239, issue.4846, pp.1389-1392, 1988. ,
Helium diffusion coefficient measurements in R7T7 nuclear glass by 3 He(d,?) 1 H nuclear reaction analysis, Journal of Nuclear Materials, vol.400, issue.2, pp.175-181, 2010. ,
Vapor hydration of a simulated borosilicate nuclear waste glass in unsaturated conditions at 50 °C and 90 °C, vol.5, pp.64538-64549, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01204735
Solid state diffusion during nuclear glass residual alteration in solution, Journal of Nuclear Materials, vol.362, pp.466-473, 2007. ,
URL : https://hal.archives-ouvertes.fr/hal-00204177
Glass-water interphase reactivity with calcium rich solutions, Geochimica et Cosmochimica Acta, vol.75, issue.15, pp.4125-4139, 2011. ,
URL : https://hal.archives-ouvertes.fr/hal-01695790
Investigating structural features which control the dissolution of bioactive phosphate glasses: Beyond the network connectivity, Journal of Non-Crystalline Solids, vol.432, pp.31-34, 2016. ,
Chemical durability of oxide glasses in aqueous solutions: A review, Journal of the American Ceramic Society, vol.91, issue.3, pp.728-735, 2008. ,
Nature and role of natural alteration gels formed on the surface of ancient volcanic glasses (Natural analogs of waste containment glasses), Journal of Nuclear Materials, vol.321, issue.1, pp.91-109, 2003. ,
Dissolution of basaltic glass in seawater: Mechanism and rate, Geochimica et Cosmochimica Acta, vol.51, issue.11, pp.2977-2990, 1987. ,
Long-term corrosion of two nuclear waste reference glasses (MW and SON68): A kinetic and mineral alteration study, Applied Geochemistry, vol.21, issue.7, pp.1152-1168, 2006. ,
URL : https://hal.archives-ouvertes.fr/hal-00082196
Kinetic aspects of basaltic glass dissolution at 90°C: role of aqueous silicon and aluminium, Chemical Geology, vol.142, issue.1-2, pp.109-126, 1997. ,
Water diffusion into silica glass: Structural changes in silica glass and their effect on water solubility and diffusivity, Journal of Non-Crystalline Solids, vol.185, issue.3, pp.203-220, 1995. ,
Leaching of borosilicate glasses. II. Model and Monte Carlo simulations, Journal of Non-Crystalline Solids, vol.343, pp.13-25, 2004. ,
Interdiffusion of hydrogen and alkali ions in a glass surface, Journal of Non-Crystalline Solids, vol.19, issue.0, pp.137-144, 1975. ,
Diffusion-controlled reaction of water with glass, Journal of Non-Crystalline Solids, vol.55, issue.1, pp.143-147, 1983. ,
A comparison of glass reaction at high and low glass surface/solution volume, Nuclear Technology, vol.104, issue.3, pp.372-384, 1993. ,
Medium-range structural order in covalent amorphous solids, Nature, vol.354, issue.6353, pp.445-452, 1991. ,
Water diffusion in the simulated French nuclear waste SON 68 contacting silica rich solutions: Experimental and modeling, Journal of Nuclear Materials, vol.355, pp.54-67, 2006. ,
URL : https://hal.archives-ouvertes.fr/in2p3-00091677
Solution effects on the surface reaction of bioactive glasses, Journal of Biomedical Materials Research, vol.27, pp.445-453, 1993. ,
Resumption of alteration at high temperature and pH: Rates measurements and comparison with initial rates, Procedia Materials Science, vol.7, pp.202-208, 2014. ,
Resumption of nuclear glass alteration: State of the art, Journal of Nuclear Materials, vol.448, issue.1-3, pp.348-363, 2014. ,
Application of the GRAAL model to leaching experiments with SON68 nuclear glass in initially pure water, Journal of Nuclear Materials, vol.392, issue.3, pp.552-567, 2009. ,
SON68 nuclear glass dissolution kinetics: Current state of knowledge and basis of the new GRAAL model, Journal of Nuclear Materials, vol.380, issue.1-3, pp.8-21, 2008. ,
URL : https://hal.archives-ouvertes.fr/hal-00569196
The effect of composition on the leaching of three nuclear waste glasses: R7T7, AVM and VRZ, Journal of Nuclear Materials, vol.346, issue.2-3, pp.194-207, 2005. ,
An experimental study of basaltic glass-H 2 O-CO 2 interaction at 22 and 50 °C: Implications for subsurface storage of CO 2, Geochimica et Cosmochimica Acta, vol.126, pp.123-145, 2014. ,
Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism, Journal of Non-Crystalline Solids, vol.356, pp.1458-1465, 2010. ,
The mechanism of borosilicate glass corrosion revisited, Geochimica et Cosmochimica Acta, vol.158, pp.112-129, 2015. ,
An international initiative on long-term behavior of high-level nuclear waste glass, Materials Today, vol.16, issue.6, pp.243-248, 2013. ,
URL : https://hal.archives-ouvertes.fr/in2p3-00864925
Effect of composition on the short-term and long-term dissolution rates of ten borosilicate glasses of increasing complexity from 3 to 30 oxides, Journal of Non-Crystalline Solids, vol.358, pp.2559-2570, 2012. ,
New Insight into the Residual Rate of Borosilicate Glasses: Effect of S/V and Glass Composition, International Journal of Applied Glass Science, vol.4, issue.4, pp.371-382, 2013. ,
Nuclear Glass Durability: New Insight into Alteration Layer Properties, Journal of Physical Chemistry C, vol.115, issue.38, pp.18696-18706, 2011. ,
Origin and consequences of silicate glass passivation by surface layers, Nature Communications, p.6, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01157456
The fate of silicon during glass corrosion under alkaline conditions: A mechanistic and kinetic study with the International Simple Glass, Geochimica et Cosmochimica Acta, vol.151, pp.68-85, 2015. ,
SON 68 nuclear glass alteration kinetics between pH 7 and pH 11.5, Journal of Nuclear Materials, vol.295, issue.1, pp.83-96, 2001. ,
Role and properties of the gel formed during nuclear glass alteration: Importance of gel formation conditions, J. Nucl. Mater, vol.298, pp.1-10, 2001. ,
Contribution of atom-probe tomography to a better understanding of glass alteration mechanisms: Application to a nuclear glass specimen altered 25 years in a granitic environment, Chemical Geology, pp.99-109, 2013. ,
A general rate equation for nuclear waste glass corrosion, Materials Research Society Symposium Proceedings, vol.44, pp.15-27, 1985. ,
Nuclear waste glasses; how durable?, Elements, vol.2, issue.6, pp.357-364, 2006. ,
First-order dissolution rate law and the role of surface layers in glass performance assessment, Journal of Nuclear Materials, vol.298, issue.1-2, pp.112-124, 2001. ,
URL : https://hal.archives-ouvertes.fr/in2p3-00021463
Nanometre-scale evidence for interfacial dissolutionreprecipitation control of silicate glass corrosion, Nature Materials, vol.14, issue.3, pp.307-311, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01929134
Unifying natural and laboratory chemical weathering with interfacial dissolution-reprecipitation: A study based on the nanometer-scale chemistry of fluid-silicate interfaces, Chemical Geology, pp.203-216, 2012. ,
URL : https://hal.archives-ouvertes.fr/hal-01834914
The story of Bioglass (R), Journal of Materials Science-Materials in Medicine, vol.17, issue.11, pp.967-978, 2006. ,
Physical chemistry of glass surface, J. Non-Cryst. Solids, vol.28, pp.83-105, 1978. ,
Experimentally determined dissolution kinetics of SON68 glass at 90°C over a silica saturation interval: Evidence against a linear rate law, Journal of Nuclear Materials, vol.439, issue.1-3, pp.137-147, 2013. ,
The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry of Silica, 1979. ,
Initial dissolution rate of the International Simple Glass as a function of pH and temperature measured using microchannel flow-through test method, International Journal of Applied Glass Science, vol.4, issue.4, pp.317-327, 2013. ,
Alteration kinetics of a simplified nuclear glass in an aqueous medium: effects of solution chemistry and of protective gel properties on diminishing the alteration rate, Journal of Nuclear Materials, vol.280, issue.2, pp.216-229, 2000. ,
Investigation of gel porosity clogging during glass leaching, Journal of Non-Crystalline Solids, vol.354, pp.4952-4958, 2008. ,
Forward dissolution rate of silicate glasses of nuclear interest in clay-equilibrated groundwater, Chemical Geology, pp.207-217, 2012. ,
Monte Carlo simulations of coupled diffusion and surface reactions during the aqueous corrosion of borosilicate glasses, Journal of Non-Crystalline Solids, vol.408, pp.142-149, 2015. ,
Dissolution Kinetics of a Simple Analogue Nuclear Waste Glass as a Function of pH, Time and Temperature, Materials Research Society Symposium Proceedings, vol.176, pp.371-381, 1989. ,
A comparative analysis of potential biosignatures in basalt glass by FIB-TEM, Chemical Geology, pp.165-175, 2012. ,
Bioactive glass-ceramics -Properties and applications, Biomaterials, vol.12, issue.2, pp.155-163, 1991. ,
Leaching of borosilicate glasses, I. Experiments. Journal of Non-Crystalline Solids, vol.343, pp.3-12, 2004. ,
Initial and long-term dissolution rates of aluminosilicate glasses enriched with Ti, Zr and Nd, Chemical Geology, vol.160, issue.1-2, pp.39-62, 1999. ,
The use of natural and archeological analogues for understanding the long-term behavior of nuclear glasses, Comptes Rendus Geoscience, vol.343, issue.2-3, pp.237-245, 2011. ,
Characteristics of Alteration Layers Formed on Simulated HLW Glass under Silica-saturated Solutions, Journal of the Australian Ceramics Society, vol.48, pp.90-95, 2012. ,
The structure of Na 2 O-Al 2 O 3 -SiO 2 glass: impact on sodium ion exchange in H 2 O and D 2 O, Journal of Non-Crystalline Solids, vol.296, issue.1-2, pp.10-26, 2001. ,
Morphology, chemistry, and spectral properties of Hawaiian rock coatings and implications for Mars, Journal of Geophysical Research-Planets, vol.112, issue.E5, 2007. ,
Enhanced dissolution of basaltic glass in brackish waters: Impact on biogeochemical cycles, Earth and Planetary Science Letters, vol.417, pp.1-8, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01769728
Alteration of Si-B-Na-Al model glass in water at 90 °C: experiments and thermodynamic modelling, Materials Research Society Symposium Proceedings, vol.757, pp.153-158, 2003. ,
Glassy Wasteforms for Nuclear Waste Immobilization, Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, vol.42, issue.4, pp.837-851, 2011. ,
The ion exchange phase in corrosion of nuclear waste glasses, Journal of Nuclear Materials, vol.358, issue.1, pp.57-68, 2006. ,
Studien über die Bildung und Umwandlung fester Körper, Zeitschrift für Physikalische Chemie, vol.22, pp.289-330, 1897. ,
Long-term alteration of basaltic glass: Mechanisms and rates, Geochimica et Cosmochimica Acta, vol.154, pp.28-48, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-02118240
Long-term dissolution rate of nuclear glasses in confined environments: does a residual chemical affinity exist, Journal of Materials Science, vol.25, issue.7, pp.3048-3052, 1990. ,
URL : https://hal.archives-ouvertes.fr/in2p3-00001097
Hydrated-layer formation during dissolution of complex silicate glasses and minerals, Geochimica et Cosmochimica Acta, vol.54, issue.7, pp.1941-1955, 1990. ,
URL : https://hal.archives-ouvertes.fr/in2p3-00001079
Combined experimental and computational approach to predict the glass-water reaction, Nuclear Technology, vol.176, issue.1, pp.22-39, 2011. ,
An experimental study of the dissolution rates of simulated aluminoborosilicate waste glasses as a function of pH and temperature under dilute conditions, Applied Geochemistry, vol.23, issue.9, pp.2559-2573, 2008. ,
Long-term Behavior Science: The cornerstone approach for reliably assessing the long-term performance of nuclear waste, Journal of Nuclear Materials, vol.420, issue.1-3, pp.182-192, 2012. ,
Composition effects on synthetic glass alteration mechanisms: Part 1, Experiments. Chemical Geology, vol.279, issue.3-4, pp.106-119, 2010. ,
Etude de la pérennité des gels d'altération des verres nucléaires, 2004. ,
Impact of soda-lime borosilicate glass composition on water penetration and water structure at the first time of alteration, Journal of Non-Crystalline Solids, vol.358, issue.22, pp.2951-2960, 2012. ,
Protective properties and dissolution ability of the gel formed during nuclear glass alteration, Journal of Nuclear Materials, vol.342, issue.1-3, pp.26-34, 2005. ,
Water penetration mechanisms in nuclear glasses by X-ray and neutron reflectometry, Journal of Non-Crystalline Solids, vol.353, pp.2221-2230, 2007. ,
X-ray reflectometry characterization of SON 68 glass alteration films, Journal of Non-Crystalline Solids, vol.325, issue.1-3, pp.113-123, 2003. ,
URL : https://hal.archives-ouvertes.fr/hal-00451624
Morphological evolution of alteration layers formed during nuclear glass alteration: new evidence of a gel as a diffusive barrier, Journal of Nuclear Materials, vol.326, issue.1, pp.9-18, 2004. ,
Role of neoformed phases on the mechanisms controlling the resumption of SON68 glass alteration in alkaline media, Journal of Nuclear Materials, vol.324, issue.2-3, pp.152-164, 2004. ,
Pseudo-equilibrium between a random system and a solution: a Monte-Carlo study of glass dissolution in water, Comptes Rendus de l'Académie des Sciences -Series IIB: Mechanics, vol.326, issue.2, pp.129-134, 1998. ,
Alteration of the oceanic crust: Implications for geochemical cycles of lithium and boron, Geochimica et Cosmochimica Acta, vol.48, issue.3, pp.557-569, 1984. ,
The role of molecular water in the leaching of glass, Physics and Chemistry of Glasses, vol.24, issue.1, pp.35-36, 1983. ,
NMR evidence for excess non-bridging oxygen in an aluminosilicate glass, Nature, vol.390, issue.6655, pp.60-62, 1997. ,
Effects of alteration product precipitation on glass dissolution, Applied Geochemistry, vol.45, pp.144-157, 2014. ,
Basaltic glass: alteration mechanisms and analogy with nuclear waste glasses, Journal of Nuclear Materials, vol.282, issue.1, pp.40-46, 2000. ,
Dissolution kinetics of basaltic glasses: control by solution chemistry and protective effect of the alteration film, Chemical Geology, vol.176, issue.1-4, pp.235-263, 2001. ,
Structural and thermodynamic explanations of Ostwald's rule, Organic Process Research & Development, vol.7, issue.6, pp.1017-1027, 2003. ,
Elemental and isotopic ( 29 Si and 18 O) tracing of glass alteration mechanisms, Geochimica et Cosmochimica Acta, vol.74, issue.12, pp.3412-3431, 2010. ,
GLAMOR -Or how we achieved a common understanding on the decrease of glass dissolution kinetics, Ceramic Transactions, vol.207, issue.s, pp.115-126, 2009. ,
Current state of knowledge of nuclear waste glass corrosion mechanisms: the case of R7T7 glass, Applied Geochemistry, vol.7, pp.13-22, 1992. ,
A fractured roman glass block altered for 1800 years in seawater: Analogy with nuclear waste glass in a deep geological repository, Geochimica et Cosmochimica Acta, vol.72, issue.22, pp.5372-5385, 2008. ,
Current understanding and remaining challenges in modeling long-term degradation of borosilicate nuclear waste glasses, International Journal of Applied Glass Science, vol.4, issue.4, pp.283-294, 2013. ,
On the pH dependence of leaching of nuclear waste glasses, Journal of Nuclear Materials, vol.116, issue.1, pp.69-77, 1983. ,
The atomic arrangement in glass, Journal of the American Chemical Society, vol.54, pp.3841-3851, 1932. ,
First-Principles Study of Hydrolysis Reaction Barriers in a Sodium Borosilicate Glass, International Journal of Applied Glass Science, vol.4, issue.4, pp.395-407, 2013. ,