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Laser-induced dealkylation of calix[4]arene-crown-6 ethers

Abstract : Selective dealkylation of dialkyl calix(4)arene monocrown-6 and calix(4)arene biscrown-6 was achieved using laser irradiation. The resulting phenolic compounds structures,studied by NMR (1H and 13C) and ESI-MS (Cs+ spiking), probably originated from theirpartial photo-Claisen rearrangement.
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https://hal-cea.archives-ouvertes.fr/cea-02356019
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Submitted on : Friday, November 8, 2019 - 3:14:56 PM
Last modification on : Tuesday, April 28, 2020 - 11:28:13 AM

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Ck. Jankowski, C. Moulin, C. Hocquelet, S. Arseneau, L. Mauclaire. Laser-induced dealkylation of calix[4]arene-crown-6 ethers. Journal of Photochemistry and Photobiology A. Chemistry, 2006, ⟨10.1016/j.jphotochem.2006.04.018⟩. ⟨cea-02356019⟩

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