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Journal articles
Spirophenylacridine‐2,7‐(diphenylphosphineoxide)‐fluorene: A Bipolar Host for High‐Efficiency Single‐Layer Blue Phosphorescent Organic Light‐Emitting Diodes
Abstract : Herein, a high-efficiency host material for single-layer phosphorescent organic light-emitting diodes (SL-PhOLEDs) is reported. This host material is synthesized via an efficient approach and is constructed on the association of an electron-rich phenylacridine unit connected by a spiro carbon atom to an electron-deficient 2,7-bis(diphenylphosphineoxide)-fluorene. In addition to a high ET value and adequate highest occupied molecular orbital/lowest unoccupied molecular orbital energy levels, the key point in this molecular design is the suitable balance between hole and electron mobilities, which leads to a high-performance blue SL-PhOLED with an external quantum efficiency of 17.6% (current efficiency = 37.8 cd A−1 and power efficiency = 37.1 lm W−1) and a low Von of 2.5 V. This performance shows that the molecular design of the present host fulfills the criteria required for high-efficiency SL-PhOLEDs. The present performance is one of the highest reported to date for blue SL-PhOLEDs and more importantly shows the potential of such a molecular design to reach very high-performance single-layer devices.
Cited literature [52 references]
https://hal-cea.archives-ouvertes.fr/cea-02354953
Contributor : Serge Palacin <>
Submitted on : Wednesday, March 25, 2020 - 10:46:22 AM
Last modification on : Friday, July 10, 2020 - 4:10:29 PM
Contributor : Serge Palacin <>
Submitted on : Wednesday, March 25, 2020 - 10:46:22 AM
Last modification on : Friday, July 10, 2020 - 4:10:29 PM
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Lucas et al-2020-Spirophenylac...
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