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Aging of Solution processed perovskite solar cells

Abstract : In recent years, perovskite (CH3NH3PbI3-XClX) solar cells have been studied steadily due to their potential properties: low-cost processing and possibility to produce large area by low temperature processes. The perovskite film used as light absorber is obtained by solution process and has a crystalline structure. Many different solvents are being developed and gradually adopted for high-performance inorganic-organic hybrid perovskite solar cells. PEDOT:PSS and PC60BM are used as hole transport layer (HTL) and electron transport layer (ETL), respectively. The size of active area is 0.28cm 2. In this study, 9.54% of power conversion efficiency (PCE) is obtained with a saturated current density (Jsc) of 15.03 mA/cm 2. The degradation of the performance of the solar cell is studied with XRD measurements as well as electrical characterizations. The perovskite solar cell performance decreases with aging time (Table 1 and Figure 1a) and XRD data show the growing of the PbI2 peak and a decreasing of the CH3NH3PbI3 (MAPbI3) peak.
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https://hal-cea.archives-ouvertes.fr/cea-02349409
Contributor : Serge Palacin <>
Submitted on : Tuesday, November 5, 2019 - 4:21:33 PM
Last modification on : Monday, February 10, 2020 - 6:13:58 PM
Long-term archiving on: : Friday, February 7, 2020 - 1:56:58 AM

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  • HAL Id : cea-02349409, version 1

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Heejae Lee, Arthur Marronnier, Denis Tondelier, Sandrine Tusseau-Nenez, Yvan Bonassieux, et al.. Aging of Solution processed perovskite solar cells. 2èmes journées Pérovskites hybrides (JPH2016), May 2016, Rennes, France. ⟨cea-02349409⟩

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