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Conference papers
Complexes of tripodal phosphine ligands: synthesis, structure and catalytic activities in the hydroboration of CO$_2$
Abstract : Tripodal ligands play a major role in transition metal chemistry by increasing the stability of their complexes and enabling a fine control of the reactivity at the metal center through their steric and electronic properties and their specifie coordination geometry. Among these ligands, triphos (MeC(CH$_2$PPh$_2$) has attracted considerable attention over the last years as it was successfully used for several applications in catalysis, including CO$_2$ hydrogenation, disproportionation of formic acid and reduction of amides. Because small changes within a ligand can induce different outcomes in a catalytic reaction, variations on the triphos backbone have been reported. In this study we report the use of PhSi(CH$_2$PPh$_2$)$_3$ and its phosphinite derivative PhSi(OPPh$_2$)$_3$h in the coordination chemistry of first-row transition metals, namely iron(II), cobalt(lI) and copper(I).
Cited literature [6 references]
https://hal-cea.archives-ouvertes.fr/cea-02342086
Contributor : Serge Palacin <>
Submitted on : Thursday, October 31, 2019 - 4:49:29 PM
Last modification on : Tuesday, July 7, 2020 - 11:42:22 AM
Long-term archiving on: : Saturday, February 1, 2020 - 4:32:39 PM
Contributor : Serge Palacin <>
Submitted on : Thursday, October 31, 2019 - 4:49:29 PM
Last modification on : Tuesday, July 7, 2020 - 11:42:22 AM
Long-term archiving on: : Saturday, February 1, 2020 - 4:32:39 PM
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Aloisi_JCC-SCF_2017.pdf
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