Skip to Main content Skip to Navigation
Conference papers

Mechanistic trends from computational chemistry for the design of redox switchable catalysts

Thibault Cantat 1
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : The search for efficient switchable catalysts is a challenging yet appealing task in polymer science as it could pave the road-to tailor-made block co-polymers. In this context, an elegant strategy relies on exploiting the reactivity of metal complexes featuring a redox-active center (Iocated either on the supporting ligand or the metal itself) to differentiate between two monomers. ln this contribution will be presented and discussed computational mechanistic results, carried out in close collaboration with the Diaconescu group at UCLA, on the use of redox switchable catalysts for the ring opening polymerization of cyclic esters with lanthanide-based catalysts.
Document type :
Conference papers
Complete list of metadata

https://hal-cea.archives-ouvertes.fr/cea-02341697
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Thursday, October 31, 2019 - 2:54:45 PM
Last modification on : Thursday, July 1, 2021 - 4:44:23 PM
Long-term archiving on: : Saturday, February 1, 2020 - 5:31:12 PM

File

Cantat_ACSSpring2017b.pdf
Files produced by the author(s)

Identifiers

  • HAL Id : cea-02341697, version 1

Citation

Thibault Cantat. Mechanistic trends from computational chemistry for the design of redox switchable catalysts. 253rd ACS Meeting, Apr 2017, San Francisco, United States. ⟨cea-02341697⟩

Share

Metrics

Record views

23

Files downloads

23