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Journal articles
SO$_2$ conversion to sulfones: development and mechanistic insights of a sulfonylative Hiyama cross-coupling
Abstract : A sulfonylative Hiyama cross-coupling reaction using gaseous SO$_2$ is described, using Pd-catalysts. The use of silicon-based nucleophiles leads to the formation of allyl sulfones under mild conditions with a broad functional group tolerance. Control experiments coupled with DFT calculations shed light on the key steps of the reaction mechanism, revealing the crucial role of a transient sulfinate anion.
Cited literature [18 references]
https://hal-cea.archives-ouvertes.fr/cea-02311034
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Thursday, October 10, 2019 - 4:11:20 PM
Last modification on : Thursday, July 1, 2021 - 4:45:09 PM
Contributor : Serge Palacin Connect in order to contact the contributor
Submitted on : Thursday, October 10, 2019 - 4:11:20 PM
Last modification on : Thursday, July 1, 2021 - 4:45:09 PM
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Adenot_ChemComm2019_V0.pdf
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