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Journal Articles Diamond and Related Materials Year : 2008

Sp3/sp2 character of the carbon and hydrogen configuration in micro- and nanocrystalline diamond

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Abstract

Hot filament and microwave plasma CVD micro- nanocrystalline diamond films are analysed by visible and ultra-violet excitation source Raman spectroscopy. The sample grain size varies from 20 nm to 2 μm. The hydrogen concentration in samples is measured by SIMS and compared to the grain size, and to the ratio of sp2 carbon bonds determined by Raman spectroscopy from the 1332 cm− 1 diamond peak and the sp2 1550 cm− 1 G band. Hydrogen concentration appears to be proportional to the sp2 bonds ratio. The 3000 cm− 1 CHx stretching mode band intensity observed on the Raman spectra is decreasing with the G band intensity. Thermal annealing modifies the sp2 phase structure and concentration, as hydrogen outdiffuses.

Dates and versions

cea-02189568 , version 1 (19-07-2019)

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D. Ballutaud, F. Jomard, T. Kociniewski, E. Rzepka, Hugues Girard, et al.. Sp3/sp2 character of the carbon and hydrogen configuration in micro- and nanocrystalline diamond. Diamond and Related Materials, 2008, 17 (4-5), pp.451-456. ⟨10.1016/j.diamond.2007.10.004⟩. ⟨cea-02189568⟩
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