F. Mathey, The organic chemistry of phospholes, Chemical Reviews, vol.88, issue.2, pp.429-453, 1988.

D. Carmichael, Phosphorus (III) Ligands in Homogeneous Catalysis: Design and Synthesis, pp.267-286, 2012.

Y. Matano and H. Imahori, Phosphole-containing calixpyrroles, calixphyrins, and porphyrins: synthesis and coordination chemistry, Accounts of Chemical Research, vol.42, issue.8, pp.1193-1204, 2009.

L. Kollar and G. Keglevich, P-Heterocycles as ligands in homogeneous catalytic reactions, Chemical Reviews, vol.110, issue.7, pp.4257-4302, 2010.

K. Fourmy, D. H. Nguyen, O. Dechy-cabaret, and M. Gouygou, Phosphole-based ligands in catalysis, Catalysis Science & Technology, vol.5, issue.9, pp.4289-4323, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01913099

P. and L. Floch, Phosphaalkene, phospholyl and phosphinine ligands: new tools in coordination chemistry and catalysis, Coordination Chemistry Reviews, vol.250, issue.5-6, pp.627-681, 2006.

M. Ogasawara, Y. Tseng, and M. Uryu, Molybdenumcatalyzed enantioselective synthesis of planar-chiral (í µí¼‚ 5 -phosphacyclopentadienyl)manganese(I) complexes and application in asymmetric catalysis, Organometallics, vol.36, issue.20, pp.4061-4069, 2017.

S. Urig, K. Fritz-wolf, and R. Réau, Undressing of phosphine gold(I) complexes as irreversible inhibitors of human disulfide reductases, Angewandte Chemie International Edition, vol.45, issue.12, pp.1881-1886, 2006.
URL : https://hal.archives-ouvertes.fr/hal-01090379

M. Arribat, E. Rémond, S. Clément, A. V. Lee, and F. Cavelier, Phospholyl(borane) amino acids and peptides: stereoselective synthesis and fluorescent properties with large stokes shift, Journal of the American Chemical Society, vol.140, issue.3, pp.1028-1034, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01708759

T. Baumgartner and R. Réau, Organophosphorus í µí¼‹-conjugated materials, Chemical Reviews, vol.106, issue.1, pp.4681-4727, 2006.
URL : https://hal.archives-ouvertes.fr/hal-01090276

M. P. Duffy, W. Delaunay, P. Bouit, and M. Hissler, í µí¼‹-Conjugated phospholes and their incorporation into devices: components with a great deal of potential, Chemical Society Reviews, vol.45, issue.19, pp.5296-5310, 2016.

A. Saito, T. Miyajima, and M. Nakashima, Acenaphtho[1,2-c]phosphole P-oxide: a phosphole-naphthalene í µí¼‹-conjugated system with high electron mobility, Chemistry -A European Journal, vol.15, issue.46, pp.10000-10004, 2009.

D. Joly, D. Tondelier, and V. Deborde, White organic light-emitting diodes based on quench-resistant fluorescent organophosphorus dopants, Advanced Functional Materials, vol.22, issue.4, pp.567-576, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00830380

T. Baumgartner, Insights on the design and electron-acceptor properties of conjugated organophosphorus materials, Accounts of Chemical Research, vol.47, issue.5, pp.1613-1622, 2014.

L. Nyulászi, Aromaticity of phosphorus heterocycles, Chemical Reviews, vol.101, issue.5, pp.1229-1246, 2001.

L. Nyulászi and Z. Benkö, Aromatic phosphorus heterocycles, Topics in Heterocyclic Chemistry, vol.19, pp.27-81, 2009.

G. Keglevich, Z. Böcskei, G. M. Keserü, K. Ujszászy, and L. ,

D. Quin, 1-(2,4,6-tri-tert-butylphenyl)-3-methylphosphole: a phosphole with a significantly flattened phosphorus pyramid having pronounced characteristics of aromaticity, Journal of the American Chemical Society, vol.119, issue.22, pp.5095-5099, 1997.

Z. Mucsi and G. Keglevich, Why are phosphole oxides unstable? The phenomenon of antiaromaticity as a destabilizing factor, European Journal of Organic Chemistry, issue.28, pp.4765-4771, 2007.

G. Bousrez, F. Jaroschik, and A. Martinez, Reactivity differences between 2,4-and 2,5-disubstituted zirconacyclopentadienes: a highly selective and general approach to 2,4-disubstituted phospholes, Dalton Transactions, vol.42, issue.30, pp.10997-11004, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00839784

G. M. Sheldrick, Crystal structure refinement with SHELXL, Acta Crystallographica Section C, vol.71, issue.1, pp.3-8, 2015.

A. Altomare, M. C. Burla, and M. Camalli, SIR97: a new tool for crystal structure determination and refinement, Journal of Applied Crystallography, vol.32, issue.1, pp.115-119, 1999.

G. Keglevich, L. Toke, Z. Böcskei, and V. Harmat, Steric hindrance in the synthesis and properties of the dimer of 1-(2,4,6-tri-tert-butylphenyl)phosphole 1-oxide, Heteroatom Chemistry, vol.8, issue.6, pp.527-531, 1997.

G. Keglevich, T. Chuluunbaatar, B. Dajka, B. Namkhainyambuu, K. Ludányi et al., Competitive [4+2] cycloadditions in equimolar mixtures of 1-arylphosphole oxides, Heteroatom Chemistry, vol.12, issue.7, pp.633-635, 2001.

D. Klintuch, K. Krekic, C. Bruhn, Z. Benk´cbenk´c, and R. Pietschnig, A rational synthetic approach to 2,5-diphenyl-í µí»½-silyl phospholes, European Journal of Inorganic Chemistry, vol.2016, issue.5, pp.718-725, 2016.

J. Hydrio, M. Gouygou, F. Dallemer, J. Daran, and G. G. Balavoine, Convenient route for the preparation of unsymmetrical phospholes via zirconacyclopentadienes, Journal of Organometallic Chemistry, vol.595, issue.2, pp.261-267, 2000.

Y. Matano, A. Saito, and T. Fukushima, Fusion of phosphole and 1,1 ? -biacenaphthene: Phosphorus(V)-containing extended í µí¼‹-systems with high electron affinity and electron mobility, Angewandte Chemie International Edition, vol.50, issue.35, pp.8016-8020, 2011.

O. Fadhel, Z. Benkö, and M. Gras, 3,4-Dithiaphosphole and 3,3 ? ,4,4 ? -tetrathia-1,1 ? -biphosphole í µí¼‹-conjugated systems: S makes the impact, Chemistry -A European Journal, vol.16, issue.37, pp.11340-11356, 2010.
URL : https://hal.archives-ouvertes.fr/hal-01104980

K. Yavari, P. Retailleau, A. Voituriez, and A. Marinetti, Heterohelicenes with embedded P-chiral 1H-phosphindole or dibenzophosphole units: diastereoselective photochemical synthesis and structural characterization, Chemistry -A European Journal, vol.19, issue.30, pp.9939-9947, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00856817

M. Kumaravel, J. T. Mague, and M. S. Balakrishna, Chalcogenide derivatives of 1,2,5-triphenyl-1H-phosphole: structure and photophysical properties, Tetrahedron Letters, vol.55, issue.18, pp.2957-2961, 2014.

A. Oukhrib, L. Bonnafoux, and A. Panossian, Novel C1-symmetric dibenzophosphole ligands: application in hydroformylation reactions, Tetrahedron, vol.70, issue.7, pp.1431-1436, 2014.
URL : https://hal.archives-ouvertes.fr/hal-00992450

D. Miesel, A. Hildebrandt, M. Korb, P. J. Low, and H. Lang, Synthesis and (spectro)electrochemical behavior of 2,5-diferrocenyl-1-phenyl-1 H-phosphole, Organometallics, vol.32, issue.10, pp.2993-3002, 2013.

K. Eichele, R. E. Wasylishen, J. M. Kessler, L. Soluji´csoluji´c, and J. H. Nelson, Phosphorus chemical shift tensors of phosphole derivatives determined by 31P NMR spectroscopy of powder samples, Inorganic Chemistry, vol.35, issue.13, pp.3904-3912, 1996.

G. M. Keseru and G. Keglevich, Stereospecific cyclodimerization of 1-methylphosphole 1-oxide: a theoretical study, Journal of Organometallic Chemistry, vol.586, issue.2, pp.166-170, 1999.

T. C. Dinadayalane and G. N. Sastry, Density functional theory study on dimerizations of phospholes, Organometallics, vol.22, issue.26, pp.5526-5533, 2003.

S. Bhai, K. Jana, and B. Ganguly, Probing the structural and electronic effects on the origin of í µí¼‹-facial stereoselectivity in 1-methylphosphole 1-oxide cycloadditions and cyclodimerization, ACS Omega, vol.3, issue.9, pp.10945-10952, 2018.

C. C. Santini, J. Fischer, F. Mathey, and A. Mitschler, Phosphole [2+2] and [4+2] dimerizations around metal carbonyl moieties, structure and chemistry of a new type of exo [4+2] dimers, Journal of the American Chemical Society, vol.102, issue.18, pp.5809-5815, 1980.

T. Möller, P. Wonneberger, N. Kretzschmar, and E. Heyhawkins, P-chiral phosphorus heterocycles: a straightforward synthesis, Chemical Communications, vol.50, issue.44, pp.5826-5828, 2014.

T. J. Barton and A. J. Nelson, Heterocyclopentadiene photochemistry, Tetrahedron Letters, vol.10, issue.57, pp.5037-5040, 1969.

M. P. Duffy, Y. Lin, L. Y. Ting, F. Mathey-;-x-=-o, and S. , New Journal of Chemistry, vol.35, issue.10, 2001.

W. L. Wilson, J. Fischer, and R. E. Wasylishen, Thermal coupling reactions of 1-phenyl-3,4-dimethylphosphole within the coordination sphere of Palladium(II), Inorganic Chemistry, vol.35, issue.6, pp.1486-1496, 1996.

H. Ji, J. H. Nelson, and A. Decian, Journal of Organometallic Chemistry, vol.529, issue.1-2, pp.395-408, 1997.

C. S. Demmer, P. Aillard, J. Febvay, P. Retailleau, A. Voituriez et al., Photochemical [2+2] cyclization of helical phosphinamides in solution and in the solid state, ChemPhotoChem, vol.1, issue.12, pp.535-538, 2017.