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Journal articles
[4+2] versus [2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes
Abstract : Phosphole P(V) derivatives are interesting building blocks for various applications from ligand synthesis to material sciences. We herein describe the preparation and characterisation of new 2,4-disubstituted oxo-, thiooxo-, and selenooxophospholes. The nature of the substituents on the phosphole ring determines the reactivity of these compounds towards homodimerization reactions. Aryl and trimethylsilyl substituted oxophospholes undergo selective [4+2] dimerization, whereas, for thiooxo-and selenooxophospholes, light-induced, selective [2+2] head-to-head dimerization occurs in the case of aryl substituents. DFT calculations provide some insights on these differences in reactivity.
Cited literature [43 references]
https://hal-cea.archives-ouvertes.fr/cea-02092318
Contributor : Serge Palacin <>
Submitted on : Monday, April 8, 2019 - 8:30:32 AM
Last modification on : Thursday, July 1, 2021 - 4:45:31 PM
Long-term archiving on: : Wednesday, July 10, 2019 - 12:23:20 PM
Contributor : Serge Palacin <>
Submitted on : Monday, April 8, 2019 - 8:30:32 AM
Last modification on : Thursday, July 1, 2021 - 4:45:31 PM
Long-term archiving on: : Wednesday, July 10, 2019 - 12:23:20 PM
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HeteroatomChem_2596405.pdf
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