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Journal articles
Covalent and Selective Grafting of Polyethylene Glycol Brushes at the Surface of ZIF-8 for the Processing of Membranes for Pervaporation
Marvin Benzaqui
1, 2
Rocio Semino
3
Florent Carn
4
Sérgio Rodrigues Tavares
3
Nicolas Menguy
5
Mónica Giménez-Marqués
2, 1
Elena Bellido
1
Patricia Horcajada
1, 6
Thomas Berthelot
7, 8
Anna Kuzminova
9
Maria Dmitrenko
9
Anastasia Penkova
9
Denis Roizard
10
Christian Serre
1, 2
Guillaume Maurin
3
Nathalie Steunou
1
7
LICSEN - Laboratoire Innovation en Chimie des Surfaces et NanoSciences
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Marvin Benzaqui 1, 2
Author
Rocio Semino 3
Author
Florent Carn 4
Author
Sérgio Rodrigues Tavares 3
Author
Nicolas F Menguy 5
Mail :
Author IdHAL : nicolas-menguy ResearcherId : http://www.researcherid.com/rid/ResearcherID F-5607-2012 ORCID : https://orcid.org/0000-0003-4613-2490
Mónica Giménez-Marqués 2, 1
Author
Elena Bellido 1
Author
Patricia Horcajada 1, 6
Author
Thomas Berthelot 7, 8
Author
Anna Kuzminova 9
Author
Maria Dmitrenko 9
Author
Anastasia Penkova 9
Author
Denis Roizard 10
Mail :
Author IdHAL : denis-roizard ORCID : https://orcid.org/0000-0003-3210-5758
Christian Serre 1, 2
Mail :
Author
Guillaume Maurin 3
Mail :
Author
Nathalie Steunou 1
Author
1
ILV - Institut Lavoisier de Versailles (Bâtiment Lavoisier
45 avenue des Etats Unis
78035 VERSAILLES CEDEX - France)
- UVSQ - Université de Versailles Saint-Quentin-en-Yvelines : UMR8180 (55 avenue de Paris - 78035 Versailles cedex - France)
- CNRS - Centre National de la Recherche Scientifique : UMR8180 (France)
2
IMAP UMR8004 FRE2000 - Institut des Matériaux Poreux de Paris (France)
- Département de Chimie - ENS Paris (24 rue Lhomond
75132 Paris Cedex 05 - France)
- ENS Paris - École normale supérieure - Paris (45, Rue d'Ulm - 75230 Paris cedex 05 - France)
- ESPCI ParisTech (France)
- CNRS - Centre National de la Recherche Scientifique : UMR8004 (France)
3
ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (Bâtiment 15 - CC003 Place Eugène Bataillon - 34095 Montpellier cedex 5 - France)
- ENSCM - Ecole Nationale Supérieure de Chimie de Montpellier (8 Rue de l'Ecole Normale 34296 Montpellier Cedex 5 - France)
- CNRS - Centre National de la Recherche Scientifique : UMR5253 (France)
- UM - Université de Montpellier (163 rue Auguste Broussonnet - 34090 Montpellier - France)
- UM1 - Université Montpellier 1 (5, boulevard Henri IV - CS 19044 - 34967 Montpellier cedex - France)
- UM2 - Université Montpellier 2 - Sciences et Techniques (Place Eugène Bataillon - 34095 Montpellier cedex 5 - France)
4
MSC (UMR_7057) - Matière et Systèmes Complexes (Université Paris Diderot, Bât. Condorcet, case postale 7056, 10 rue Alice Domon et Léonie Duquet, 75205 PARIS Cedex 13 - France)
- CNRS - Centre National de la Recherche Scientifique : UMR_7057 (France)
- UPD7 - Université Paris Diderot - Paris 7 : UMR_7057 (5 rue Thomas-Mann - 75205 Paris cedex 13 - France)
5
IMPMC - Institut de minéralogie, de physique des matériaux et de cosmochimie (Tour 23 - Barre 22-23 - 4e étage - BC 115 - 4 place Jussieu - 75252 Paris - France)
- MNHN - Muséum national d'Histoire naturelle (57, rue Cuvier - 75231 Paris Cedex 05 - France)
- UPMC - Université Pierre et Marie Curie - Paris 6 : UM120 (4 place Jussieu - 75005 Paris - France)
- Institut de recherche pour le développement [IRD] : UR206 (France)
- CNRS - Centre National de la Recherche Scientifique : UMR7590 (France)
6
Instituto IMDEA Energy (France)
7
LICSEN - Laboratoire Innovation en Chimie des Surfaces et NanoSciences (LICSEN, NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91190 Gif sur Yvette - France)
- NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M) (NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91190 Gif sur Yvette - France)
- IRAMIS - Institut Rayonnement Matière de Saclay : DRF/IRAMIS (91191 Gif-sur-Yvette, France - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- CNRS - Centre National de la Recherche Scientifique : UMR3685 (France)
- IRAMIS - Institut Rayonnement Matière de Saclay : DRF/IRAMIS (91191 Gif-sur-Yvette, France - France)
8
SPCSI - Service de Physique et de Chimie des Surfaces et Interfaces (DSM/DRECAM/SPCSI, CEA Saclay F-91191 Gif sur Yvette - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DSM/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
9
SPBU - Saint Petersburg University (Russia)
10
LRGP - Laboratoire Réactions et Génie des Procédés (Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex - France)
- UL - Université de Lorraine (34 cours Léopold - CS 25233 - 54052 Nancy cedex - France)
- CNRS - Centre National de la Recherche Scientifique : UMR7274 (France)
Abstract : The so-called Graftfast reaction in water and at room temperature (RT) was applied to graft polyethylene glycol (PEG) at the surface of the microporous zeolitic imidazolate framework ZIF-8 nanoparticles (NPs) using acrylPEG of different chain lengths (480 Da and 5 kDa). In comparison to non-modified ZIF-8 NPs, both chemical and colloidal stabilities of PEGylated ZIF-8 NPs are significantly enhanced in water. A series of colloidal complex fluids by mixing PEG grafted ZIF-8 (i. e. PEG-g-ZIF-8) NPs with different amounts of polyvinylalcohol (PVA) was prepared and characterized by advanced characterization tools such as dynamic light scattering (DLS) and small-angle X-ray scattering (SAXS) thereby showing their long-term colloidal stability. Finally, dense and supported mixed matrix membranes were cast from PEG-g-ZIF-8/PVA solutions and have shown high performance in isopropanol (IPA) dehydration by pervaporation. The permeation flux of the supported MMM (i. e. 0.091 kg/(m$^2$h) is eleven times higher than that of the pure PVA membrane and these MMMs present a high separation factor (i. e. 7326). These transport properties are presumably due to the molecular sieving effects induced by ZIF-8 and the good interfacial properties of the membrane. The computational exploration of the ZIF-8/PVA and PEG/PVA interfaces provides a microscopic scale explanation for the enhanced compatibility of PVA with the PEGylated MOF when compared to that for the composite based on the bare ZIF-8 as a filler.
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Complete list of metadatas
https://hal-cea.archives-ouvertes.fr/cea-02072200
Contributor : Serge Palacin <>
Submitted on : Tuesday, March 19, 2019 - 8:47:17 AM
Last modification on : Saturday, April 11, 2020 - 2:12:10 AM
Document(s) archivé(s) le : Thursday, June 20, 2019 - 12:47:23 PM
Contributor : Serge Palacin <>
Submitted on : Tuesday, March 19, 2019 - 8:47:17 AM
Last modification on : Saturday, April 11, 2020 - 2:12:10 AM
Document(s) archivé(s) le : Thursday, June 20, 2019 - 12:47:23 PM
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Benzaqui_ACSSCE2019_V0.pdf
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Identifiers
- HAL Id : cea-02072200, version 1
- DOI : 10.1021/acssuschemeng.8b05587
Collections
CEA | CNRS | ESPCI | ALLINSP | DSM-IRAMIS | UVSQ | PUBNIMBE | UNIV-LORRAINE | IRAMIS-NIMBE | CEA-UPSAY | ILV | PSL | IRD | INC-CNRS | CHIMIE | UNIV-MONTPELLIER | LRGP-UL | CEA-DRF | ICG | ENS-PARIS | SORBONNE-UNIVERSITE | PARISTECH | UNIV-PARIS7 | SPCSI | USPC | UNIV-PARIS-SACLAY | IMPMC | MNHN | SU-SCIENCES | UP-SCIENCES
Citation
Marvin Benzaqui, Rocio Semino, Florent Carn, Sérgio Rodrigues Tavares, Nicolas Menguy, et al.. Covalent and Selective Grafting of Polyethylene Glycol Brushes at the Surface of ZIF-8 for the Processing of Membranes for Pervaporation. ACS Sustainable Chemistry & Engineering, American Chemical Society, 2019, 7, pp.6629-6639. ⟨10.1021/acssuschemeng.8b05587⟩. ⟨cea-02072200⟩
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