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Perylene-Based All-Organic Redox Battery with Excellent Cycling Stability

Adriana Iordache 1 Virginie Delhorbe 1 Michel Bardet 2 Lionel Dubois 3 Thibaut Gutel 1 Lionel Picard 1
2 RM - Magnetic Resonance
MEM - Modélisation et Exploration des Matériaux : DRF/IRIG/MEM
3 RICC - Reconnaissance Ionique et Chimie de Coordination
SYMMES - SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé : DRF/INAC/SYMMES
Abstract : Organic materials derived from biomass can constitute a viable option as replacements for inorganic materials in lithium-ion battery electrodes owing to their low production costs, recyclability, and structural diversity. Among them, conjugated carbonyls have become the most promising type of organic electrode material as they present high theoretical capacity, fast reaction kinetics, and quasi-infinite structural diversity. In this letter, we report a new perylene-based all-organic redox battery comprising two aromatic conjugated carbonyl electrode materials, the prelithiated tetra-lithium perylene-3,4,9,10-tetracarboxylate (PTCLi6) as negative electrode material and the poly(N-n-hexy1-3,4,9,10-perylene tetracarboxylic)imide (PTCI) as positive electrode material. The resulting battery shows promising long-term cycling stability up to 200 cycles. In view of the enhanced cycling performances, the two organic materials studied herein are proposed as suitable candidates for the development of new all-organic lithium-ion batteries.
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Submitted on : Thursday, July 26, 2018 - 3:16:16 PM
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Adriana Iordache, Virginie Delhorbe, Michel Bardet, Lionel Dubois, Thibaut Gutel, et al.. Perylene-Based All-Organic Redox Battery with Excellent Cycling Stability. ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2016, 8 (35), pp.22762-22767. ⟨10.1021/acsami.6b07591⟩. ⟨cea-01849853⟩



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