Ex situ solid electrolyte interphase synthesis via radiolysis of Li-ion battery anode–electrolyte system for improved coulombic efficiency

Fanny Varenne; John Alper; Frederic Miserque; Chandra Sekhar Bongu; Adrien Boulineau; Jean-Frederic Martin; Vincent Dauvois; Alexandre Demarque; Mickaël Bouhier; Florent Boismain; Sylvain Franger; Nathalie Herlin-Boime; Sophie Le Caer

doi:10.1039/C8SE00257F

Ex situ solid electrolyte interphase synthesis via radiolysis of Li-ion battery anode–electrolyte system for improved coulombic efficiency

Fanny Varenne ¹ John Alper ² Frederic Miserque ³ Chandra Sekhar Bongu ¹ Adrien Boulineau ⁴ Jean-Frederic Martin ⁴ Vincent Dauvois ⁵ Alexandre Demarque ⁶ Mickaël Bouhier ¹ Florent Boismain ² Sylvain Franger ⁷ Nathalie Herlin-Boime ² Sophie Le Caer ¹

1 LIONS - Laboratoire Interdisciplinaire sur l'Organisation Nanométrique et Supramoléculaire

NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)

2 LEDNA - Laboratoire Edifices Nanométriques

NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)

3 DEN/DANS/DEPC/SCCME/LECA

4 LITEN - Laboratoire d'Innovation pour les Technologies des Energies Nouvelles et les nanomatériaux

5 SECR - Service d'Etudes du Comportement des Radionucléides

DPC - Département de Physico-Chimie : DEN/DPC

6 Laboratoire de Chimie Physique/ELYSE

7 ICMMO - Institut de Chimie Moléculaire et des Matériaux d'Orsay

Abstract : The radiolysis of a mixed solvent electrolyte–carbon anode material is investigated for the first time. The present work demonstrates the radiolytic growth of an SEI with a chemical composition similar to that formed during electrochemical cycling, as determined by XPS. The quantity of the SEI increases with increasing irradiation dose. Degradation products formed in the liquid and gas phase are also identified as matching those formed during electrochemical cycling. TEM results support the XPS results of increasing SEI content with increasing irradiation dose. Electrochemical characterization by galvanostatic cycling of test cells indicates that the radiolysis generated SEI greatly improves first cycle efficiency of the materials assembled in half cells, and impedance spectroscopy supports the result with an increase in resistivity observed for irradiated samples. This first study opens the door to the use of irradiation tools for the artificial generation of an SEI and for producing LIB anode materials with improved performance.

Type de document :

Article dans une revue

Sustainable Energy & Fuels, Royal Society of Chemistry, 2018, 2, pp.2100-2108. 〈https://pubs.rsc.org/en/content/articlelanding/2018/se/c8se00257f#!divAbstract〉. 〈10.1039/C8SE00257F〉

Domaine :

Chimie / Matériaux

Chimie / Chimie inorganique

Chimie / Chimie théorique et/ou physique

Liste complète des métadonnées

https://hal-cea.archives-ouvertes.fr/cea-01849069
Contributeur : Serge Palacin <>
Soumis le : mercredi 25 juillet 2018 - 14:37:32
Dernière modification le : lundi 11 février 2019 - 16:48:01

Ex situ solid electrolyte interphase synthesis via radiolysis of Li-ion battery anode–electrolyte system for improved coulombic efficiency

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Ex situ solid electrolyte interphase synthesis via radiolysis of Li-ion battery anode–electrolyte system for improved coulombic efficiency

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