Iridium(iii) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions

Elodie Sauvageot; Ronan Marion; Fabien Sguerra; Adèle Grimault; Richard Daniellou; Matthieu Hamel; Sylvain Gaillard; Jean-Luc Renaud

Iridium(iii) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions

Elodie Sauvageot ¹ Ronan Marion ¹ Fabien Sguerra ² Adèle Grimault ¹ Richard Daniellou ³ Matthieu Hamel ² Sylvain Gaillard ¹ Jean-Luc Renaud ¹

1 LCMT - Laboratoire de chimie moléculaire et thioorganique

2 LCAE - Laboratoire Capteurs et Architectures Electroniques

DM2I - Département Métrologie Instrumentation & Information : DRT/LIST/DM2I

3 ICOA - Institut de Chimie Organique et Analytique

Abstract : Two new series of cyclometalated iridium(III) complexes bearing a dipyridylamine as the N^N ligand have been prepared and fully characterized. After investigation of their photophysical properties, their catalytic activities have been evaluated in a model photoredox reaction and compared with the commercially available [Ir(ppy)2 (dtbbpy)][PF6] complex

Document type :

Journal articles

Domain :

Chemical Sciences / Organic chemistry

Chemical Sciences / Coordination chemistry

Engineering Sciences [physics] / Optics / Photonic

Complete list of metadatas

https://hal-cea.archives-ouvertes.fr/cea-01825703
Contributor : Bruno Savelli <>
Submitted on : Thursday, June 28, 2018 - 3:18:43 PM
Last modification on : Friday, July 12, 2019 - 1:01:57 AM

Iridium(iii) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions

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Iridium(iii) dipyridylamine complexes: synthesis, characterization and catalytic activities in photoredox reactions

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