Flexible organic–inorganic hybrid layer encapsulation for organic opto-electronic devices

Subimal Majee; Maria Fátima Cerqueira; Denis Tondelier; Bernard Geffroy; Yvan Bonnassieux; Pedro Alpuim; Jean Eric Bouree

doi:10.1016/j.porgcoat.2014.11.015

Flexible organic–inorganic hybrid layer encapsulation for organic opto-electronic devices

Subimal Majee ¹ Maria Fátima Cerqueira ² Denis Tondelier ¹ Bernard Geffroy ³ Yvan Bonnassieux ¹ Pedro Alpuim ^{4, 2} Jean Eric Bouree ¹

1 LPICM - Laboratoire de physique des interfaces et des couches minces [Palaiseau]

2 CFUM - Centro de Física da Universidade do Minho

3 LICSEN - Laboratoire Innovation en Chimie des Surfaces et NanoSciences

NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)

4 International Iberian Nanotechnology Laboratory, 4715-330 Braga, Portugal

Abstract : In this work we produce and study the flexible organic–inorganic hybrid moisture barrier layers for the protection of air sensitive organic opto-electronic devices. The inorganic amorphous silicon nitride layer (SiN$_x$:H) and the organic PMMA [poly (methyl methacrylate)] layer are deposited alternatingly by using hot wire chemical vapor deposition (HW-CVD) and spin-coating techniques, respectively. The effect of organic–inorganic hybrid interfaces is analyzed for increasing number of interfaces. We produce highly transparent (∼80% in the visible region) hybrid structures. The morphological properties are analyzed providing a good basis for understanding the variation of the water vapor transmission rate (WVTR) values. A minimum WVTR of 4.5×10$^{−5}$ g/m$^2$ day is reported at the ambient atmospheric conditions for 7 organic/inorganic interfaces. The hybrid barriers show superb mechanical flexibility which confirms their high potential for flexible applications.

Type de document :

Article dans une revue

Progress in Organic Coatings, 2014, 80, pp.27 - 32. 〈10.1016/j.porgcoat.2014.11.015〉

Domaine :

Chimie / Matériaux

Liste complète des métadonnées

https://hal-cea.archives-ouvertes.fr/cea-01758732
Contributeur : Serge Palacin <>
Soumis le : mercredi 4 avril 2018 - 17:14:06
Dernière modification le : jeudi 10 mai 2018 - 01:58:20

Flexible organic–inorganic hybrid layer encapsulation for organic opto-electronic devices

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