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Journal articles
Corrosion at the carbon steel-clay borehole water interface under anoxic alkaline and fluctuating temperature conditions
Abstract : Coupons of carbon steel were corroded in situ in anoxic clay porewater under slightly alkaline conditions. Sample damage was less than 1 $\mu$m for 9 months at 85 °C only, and corrosion interfaces were covered by a thin, protective layer of Fe-silicate. The damage was more significant for samples exposed to room temperature transients (up to 38 μm for two years), and the long-term surface differentiated in cathodic (Fe-silicate covered) areas and anodic crevices filled with siderite, chukanovite, $\beta$-Fe$_2$(OH)$_3$Cl, and covered by tubercles. Sulfide compounds were detected, and were related to the metabolism of sulfate-reducing prokaryotes detected by microbiological techniques.
Cited literature [91 references]
https://hal-cea.archives-ouvertes.fr/cea-01736952
Contributor : Serge Palacin <>
Submitted on : Monday, January 6, 2020 - 3:51:34 PM
Last modification on : Saturday, October 3, 2020 - 3:28:44 AM
Long-term archiving on: : Tuesday, April 7, 2020 - 11:13:10 PM
Contributor : Serge Palacin <>
Submitted on : Monday, January 6, 2020 - 3:51:34 PM
Last modification on : Saturday, October 3, 2020 - 3:28:44 AM
Long-term archiving on: : Tuesday, April 7, 2020 - 11:13:10 PM
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