S. Gin, An international initiative on long-term behavior of high-level nuclear waste glass, Materials Today, vol.16, issue.6, pp.243-248, 2013.
DOI : 10.1016/j.mattod.2013.06.008
URL : https://hal.archives-ouvertes.fr/in2p3-00864925

B. Grambow, Nuclear waste glasses?how durable? Elements 2, pp.357-364, 2006.
DOI : 10.2113/gselements.2.6.357

J. D. Vienna, J. V. Ryan, S. Gin, and Y. Inagaki, Current Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses, International Journal of Applied Glass Science, vol.420, issue.1-3, pp.283-294, 2013.
DOI : 10.1016/j.jnucmat.2011.09.012

C. M. Jantzen, K. G. Brown, and J. B. Pickett, Durable Glass for Thousands of Years, International Journal of Applied Glass Science, vol.757, issue.1, pp.38-62, 2010.
DOI : 10.1007/978-1-4615-9107-8_7

S. Gin, Atom-Probe Tomography, TEM and ToF-SIMS study of borosilicate glass alteration rim: A multiscale approach to investigating rate-limiting mechanisms, Geochimica et Cosmochimica Acta, vol.202, pp.57-76, 2017.
DOI : 10.1016/j.gca.2016.12.029

T. Charpentier, Self-healing capacity of nuclear glass observed by NMR spectroscopy, Scientific Reports, vol.53, issue.1, p.25499, 2016.
DOI : 10.1021/ic5007555
URL : https://hal.archives-ouvertes.fr/cea-01312958

C. Mendoza, Oxide glass structure evolution under swift heavy ion irradiation, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, vol.325, pp.54-65, 2014.
DOI : 10.1016/j.nimb.2014.02.002
URL : https://hal.archives-ouvertes.fr/hal-01092621

S. Gin, Origin and consequences of silicate glass passivation by surface layers, Nature Communications, vol.2, issue.1, pp.1-8, 2015.
DOI : 10.1016/S0968-4328(99)00005-0
URL : https://hal.archives-ouvertes.fr/hal-01157456

S. Gin, The fate of silicon during glass corrosion under alkaline conditions: A mechanistic and kinetic study with the International Simple Glass, Geochimica et Cosmochimica Acta, vol.151, pp.68-85, 2015.
DOI : 10.1016/j.gca.2014.12.009

L. Neill, Various effects of magnetite on international simple glass (ISG) dissolution: implications for the long-term durability of nuclear glasses, npj Materials Degradation, vol.7, issue.1, pp.1-11, 2017.
DOI : 10.1038/nmat2301

S. Amma, J. Luo, S. H. Kim, and C. G. Pantano, Effects of fictive temperature on the leaching of soda lime silica glass surfaces, Journal of the American Ceramic Society, vol.81, issue.204, pp.1424-1431, 2017.
DOI : 10.1007/BF00371154

L. Cormier, L. Galoisy, D. Ghaleb, and G. Calas, Short- and medium-range structural order around cations in glasses: a??multidisciplinary approach, Comptes Rendus de l'Acad??mie des Sciences - Series IV - Physics-Astrophysics, vol.2, issue.2, pp.249-262, 2001.
DOI : 10.1016/S1296-2147(01)01168-4
URL : https://hal.archives-ouvertes.fr/hal-00085659

J. M. Delaye, Modeling of multicomponent glasses: a review, Current Opinion in Solid State and Materials Science, vol.5, issue.5, pp.451-454, 2001.
DOI : 10.1016/S1359-0286(01)00028-6

A. Soleilhavoup, J. M. Delaye, F. Angeli, D. Caurant, and T. Charpentier, Contribution of first-principles calculations to multinuclear NMR analysis of borosilicate glasses, Magnetic Resonance in Chemistry, vol.129, issue.S1, pp.159-170, 2010.
DOI : 10.1002/bbpc.19961000812

M. Barlet, A. Kerrache, J. Delaye, and C. L. Rountree, SiO2???Na2O???B2O3 density: A comparison of experiments, simulations, and theory, Journal of Non-Crystalline Solids, vol.382, pp.32-44, 2013.
DOI : 10.1016/j.jnoncrysol.2013.09.022
URL : https://hal.archives-ouvertes.fr/cea-01507179

L. Kieu, J. Delaye, L. Cormier, and C. Stolz, Development of empirical potentials for sodium borosilicate glass systems, Journal of Non-Crystalline Solids, vol.357, issue.18, pp.3313-3321, 2011.
DOI : 10.1016/j.jnoncrysol.2011.05.024
URL : https://hal.archives-ouvertes.fr/hal-00640118

J. Du, Challenges in molecular dynamics simulations of multicomponent oxide glasses. First-Principles modeling of binary chalcogenides: Recent accomplishments and new achievements, pp.157-180, 2015.

L. Deng and J. Du, Development of effective empirical potentials for molecular dynamics simulations of the structures and properties of boroaluminosilicate glasses, Journal of Non-Crystalline Solids, vol.453, pp.177-194, 2016.
DOI : 10.1016/j.jnoncrysol.2016.09.021

S. Gin, The controversial role of inter-diffusion in glass alteration, Chemical Geology, vol.440, pp.115-123, 2016.
DOI : 10.1016/j.chemgeo.2016.07.014

K. Ferrand, A. Abdelouas, and B. Grambow, Water diffusion in the simulated French nuclear waste glass SON 68 contacting silica rich solutions: Experimental and modeling, Journal of Nuclear Materials, vol.355, issue.1-3, pp.54-67, 2006.
DOI : 10.1016/j.jnucmat.2006.04.005
URL : https://hal.archives-ouvertes.fr/in2p3-00091677

F. Angeli, T. Charpentier, D. De-ligny, and C. Cailleteau, Boron Speciation in Soda-Lime Borosilicate Glasses Containing Zirconium, Journal of the American Ceramic Society, vol.107, issue.[14], pp.2693-2704, 2010.
DOI : 10.1103/PhysRevB.23.2513

F. Angeli, Influence of lanthanum on borosilicate glass structure: A multinuclear MAS and MQMAS NMR investigation, Journal of Non-Crystalline Solids, vol.376, pp.189-198, 2013.
DOI : 10.1016/j.jnoncrysol.2013.05.042

G. Engelhardt and D. Michel, High Resolution Solid State NMR of Silicates and Zeolites, 1987.

O. B. Lapina, D. F. Khabibulin, and V. Terskikh, Multinuclear NMR study of silica fiberglass modified with zirconia, Solid State Nuclear Magnetic Resonance, vol.39, issue.3-4, pp.47-57, 2011.
DOI : 10.1016/j.ssnmr.2010.12.002

J. Schneider, Qn distribution in stoichiometric silicate glasses: thermodynamic calculations and 29Si high resolution NMR measurements, Journal of Non-Crystalline Solids, vol.325, issue.1-3, pp.164-178, 2003.
DOI : 10.1016/S0022-3093(03)00332-6

F. Angeli, M. Gaillard, P. Jollivet, and T. Charpentier, Influence of glass composition and alteration solution on leached silicate glass structure: A solid-state NMR investigation, Geochimica et Cosmochimica Acta, vol.70, issue.10, pp.2577-2590, 2006.
DOI : 10.1016/j.gca.2006.02.023

F. Angeli, M. Gaillard, P. Jollivet, and T. Charpentier, Contribution of 43Ca MAS NMR for probing the structural configuration of calcium in glass, Chemical Physics Letters, vol.440, issue.4-6, pp.324-328, 2007.
DOI : 10.1016/j.cplett.2007.04.036

S. Gin, X. Beaudoux, F. Angeli, C. Jegou, and N. Godon, Effect of composition on the short-term and long-term dissolution rates of ten borosilicate glasses of increasing complexity from 3 to 30 oxides, Journal of Non-Crystalline Solids, vol.358, issue.18-19, pp.2559-2570, 2012.
DOI : 10.1016/j.jnoncrysol.2012.05.024

A. Fluegel, Global Model for Calculating Room-Temperature Glass Density from the Composition, Journal of the American Ceramic Society, vol.47, issue.4, pp.2622-2625, 2007.
DOI : 10.1016/j.jnoncrysol.2006.05.009

K. Iacovino, Glass Density Calc v3.2, 2017.

P. Jollivet, Effect of clayey groundwater on the dissolution rate of the simulated nuclear waste glass SON68, Journal of Nuclear Materials, vol.420, issue.1-3, pp.508-518, 2012.
DOI : 10.1016/j.jnucmat.2011.10.026

M. L. Connolly, Analytical molecular surface calculation, Journal of Applied Crystallography, vol.16, issue.5, pp.548-558, 1983.
DOI : 10.1107/S0021889883010985
URL : http://journals.iucr.org/j/issues/1983/05/00/a22969/a22969.pdf

Y. Inagaki, T. Kikunaga, K. Idemitsu, and T. Arima, Initial Dissolution Rate of the International Simple Glass as a Function of pH and Temperature Measured Using Microchannel Flow-Through Test Method, International Journal of Applied Glass Science, vol.296, issue.331, pp.317-327, 2013.
DOI : 10.1016/S0022-3093(01)00890-0

M. Fournier, P. Frugier, and S. Gin, Resumption of Alteration at High Temperature and pH: Rates Measurements and Comparison with Initial Rates, Procedia Materials Science, vol.7, pp.202-208, 2014.
DOI : 10.1016/j.mspro.2014.10.026

Y. Xiang, J. Du, M. M. Smedskjaer, and J. Mauro, Structure and properties of sodium aluminosilicate glasses from molecular dynamics simulations, The Journal of Chemical Physics, vol.91, issue.1, p.44507, 2013.
DOI : 10.2138/am.2009.3177

X. Lu, Effects of boron oxide substitution on the structure and bioactivity of SrO-containing bioactive glasses, Journal of Materials Science, vol.357, issue.15, pp.8793-8811, 2017.
DOI : 10.1016/j.jnoncrysol.2010.11.098

G. N. Greaves, A. Fontaine, P. Lagarde, D. Raoux, and S. J. Gurman, Local structure of silicate glasses, Nature, vol.41, issue.36, pp.611-616, 1981.
DOI : 10.1038/293611a0

D. A. Mckeown, G. A. Waychunas, and G. E. Brown, Exafs and xanes study of the local coordination environment of sodium in a series of silica-rich glasses and selected minerals within the Na2O???Al2O3???SiO2 system, Journal of Non-Crystalline Solids, vol.74, issue.2-3, pp.325-348, 1984.
DOI : 10.1016/0022-3093(85)90078-X

P. Jollivet, An enhanced resolution of the structural environment of zirconium in borosilicate glasses, Journal of Non-Crystalline Solids, vol.381, pp.40-47, 2013.
DOI : 10.1016/j.jnoncrysol.2013.09.013
URL : https://hal.archives-ouvertes.fr/hal-01015419

E. Gambuzzi, Probing silicon and aluminium chemical environments in silicate and aluminosilicate glasses by solid state NMR spectroscopy and accurate first-principles calculations, Geochimica et Cosmochimica Acta, vol.125, pp.170-185, 2014.
DOI : 10.1016/j.gca.2013.10.025
URL : https://hal.archives-ouvertes.fr/hal-01157475

P. Zapol, H. He, K. D. Kwon, and L. J. Criscenti, First-Principles Study of Hydrolysis Reaction Barriers in a Sodium Borosilicate Glass, International Journal of Applied Glass Science, vol.23, issue.350, pp.395-407, 2013.
DOI : 10.1016/j.apgeochem.2008.05.006

A. Quintas, NMR Study of a Rare-Earth Aluminoborosilicate Glass with Varying CaO-to-Na2O Ratio, Applied Magnetic Resonance, vol.213, issue.96, pp.613-634, 2007.
DOI : 10.1007/s00723-007-0041-0

T. Chave, P. Frugier, S. Gin, and A. Ayral, Glass???water interphase reactivity with calcium rich solutions, Geochimica et Cosmochimica Acta, vol.75, issue.15, pp.4125-4139, 2011.
DOI : 10.1016/j.gca.2011.05.005
URL : https://hal.archives-ouvertes.fr/hal-01695790

J. Rimstidt, Geochemical Rate Models: An Introduction to Geochemical Kinetics, 2014.
DOI : 10.1017/CBO9781139342773

T. Chave, P. Frugier, A. Ayral, and S. Gin, Solid state diffusion during nuclear glass residual alteration in solution, Journal of Nuclear Materials, vol.362, issue.2-3, pp.466-473, 2007.
DOI : 10.1016/j.jnucmat.2007.01.095
URL : https://hal.archives-ouvertes.fr/hal-00204177

L. L. Hench, Sol-Gel Silica: Properties, Processing, and Technology Transfer, 1998.

F. M. Ernsberger, Molecular Water in Glass, Journal of the American Ceramic Society, vol.48, issue.12, pp.91-92, 1977.
DOI : 10.1111/j.1151-2916.1977.tb16110.x

C. Wu, Nature of Incorporated Water in Hydrated Silicate Glasses, Journal of the American Ceramic Society, vol.32, issue.3, pp.453-457, 1980.
DOI : 10.1111/j.1151-2916.1980.tb10211.x

S. Newman, E. Stolper, and S. Epstein, Measurement of water in rhyolitic glasses: Calibration of an infrared spectroscopict technique, Am. Mineral, vol.71, pp.1527-1541, 1986.

J. Sowerby and H. Keppler, Water speciation in rhyolitic melt determined by in-situ infrared spectroscopy, American Mineralogist, vol.84, issue.11-12, pp.1843-1849, 1999.
DOI : 10.2138/am-1999-11-1211

B. C. Schmidt, H. Behrens, T. Riemer, R. Kappes, and R. Dupree, Quantitative determination of water speciation in aluminosilicate glasses: a comparative NMR and IR spectroscopic study, Chemical Geology, vol.174, issue.1-3, pp.195-208, 2001.
DOI : 10.1016/S0009-2541(00)00316-8

T. Yokoyama, S. Okumura, and S. Nakashima, Hydration of rhyolitic glass during weathering as characterized by IR microspectroscopy, Geochimica et Cosmochimica Acta, vol.72, issue.1, pp.117-125, 2008.
DOI : 10.1016/j.gca.2007.10.018

F. Brunet, T. Charpentier, L. Caer, S. Renault, and J. P. , Solid-state NMR characterization of a controlled-pore glass and of the effects of electron irradiation, Solid State Nuclear Magnetic Resonance, vol.33, issue.1-2, pp.1-11, 2008.
DOI : 10.1016/j.ssnmr.2007.12.001

L. Losq, C. Cody, G. D. Mysen, and B. , Alkali influence on the water speciation and the environment of protons in silicate glasses revealed by 1H MAS NMR spectroscopy, American Mineralogist, vol.100, issue.2-3, pp.466-473, 2015.
DOI : 10.2138/am-2015-5004

X. Xue and M. Kanzaki, Structure of hydrous aluminosilicate glasses along the diopside???anorthite join: A comprehensive one- and two-dimensional 1H and 27Al NMR study, Geochimica et Cosmochimica Acta, vol.72, issue.9, pp.2331-2348, 2008.
DOI : 10.1016/j.gca.2008.01.022

W. Smith and T. Forester, DL_POLY_2.0: A general-purpose parallel molecular dynamics simulation package, Journal of Molecular Graphics, vol.14, issue.3, pp.136-141, 1996.
DOI : 10.1016/S0263-7855(96)00043-4
URL : https://hal.archives-ouvertes.fr/hal-01536043

M. Fournier, Glass dissolution rate measurement and calculation revisited, Journal of Nuclear Materials, vol.476, pp.140-154, 2016.
DOI : 10.1016/j.jnucmat.2016.04.028

C. Cailleteau, Insight into silicate-glass corrosion mechanisms, Nature Materials, vol.31, issue.12, pp.978-983, 2008.
DOI : 10.1016/S0016-7037(01)00710-4

B. Wild, pH-dependent control of feldspar dissolution rate by altered surface layers, Chemical Geology, vol.442, pp.148-159, 2016.
DOI : 10.1016/j.chemgeo.2016.08.035

H. Aguiar, J. Serra, P. González, and B. León, Structural study of sol???gel silicate glasses by IR and Raman spectroscopies, Journal of Non-Crystalline Solids, vol.355, issue.8, pp.475-480, 2009.
DOI : 10.1016/j.jnoncrysol.2009.01.010

K. M. Davis and M. Tomozawa, An infrared spectroscopic study of water-related species in silica glasses, Journal of Non-Crystalline Solids, vol.201, issue.3, pp.177-198, 1996.
DOI : 10.1016/0022-3093(95)00631-1

F. H. Larsen, 29Si and 17O (Q)CPMG-MAS solid-state NMR experiments as an optimum approach for half-integer nuclei having long T1 relaxation times, Chemical Physics Letters, vol.357, issue.5-6, pp.403-408, 2002.
DOI : 10.1016/S0009-2614(02)00520-1
URL : https://curis.ku.dk/ws/files/36017347/fhl_CPL_2002.pdf

D. Massiot, Modelling one- and two-dimensional solid-state NMR spectra, Magnetic Resonance in Chemistry, vol.320, issue.1, pp.70-76, 2002.
DOI : 10.1016/S0009-2614(00)00277-3