Synthesis of Aromatic Sulfones from SO 2 and Organosilanes Under Metal-free Conditions

Niklas Von wolff 1 Joëlle Char 1 Xavier Frogneux 1 Thibault Cantat 1
1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)
NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)
Abstract : The conversion of SO2 to arylsulfones has been achieved for the first time under metal-free conditions, by reacting SO2 with (hetero)arylsilanes and alkylhalides, in the presence of a fluoride source. The mechanism of this transformation has been elucidated based on DFT calculations, which highlight the influence of SO2 in promoting C–Si bond cleavage.
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Submitted on : Friday, December 8, 2017 - 6:08:14 PM
Last modification on : Thursday, February 7, 2019 - 5:09:55 PM

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Niklas Von wolff, Joëlle Char, Xavier Frogneux, Thibault Cantat. Synthesis of Aromatic Sulfones from SO 2 and Organosilanes Under Metal-free Conditions. Angewandte Chemie, Wiley-VCH Verlag, 2017, 129 (20), pp.5708 - 5711. ⟨10.1002/ange.201702311⟩. ⟨cea-01659794⟩

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