Synthesis of Aromatic Sulfones from SO 2 and Organosilanes Under Metal-free Conditions

Niklas Von wolff (1) , Joëlle Char (1) , Xavier Frogneux (1) , Thibault Cantat (1)

1 LCMCE - Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF)

The conversion of SO2 to arylsulfones has been achieved for the first time under metal-free conditions, by reacting SO2 with (hetero)arylsilanes and alkylhalides, in the presence of a fluoride source. The mechanism of this transformation has been elucidated based on DFT calculations, which highlight the influence of SO2 in promoting C–Si bond cleavage.

Domains: Material chemistry

Niklas Von wolff, Joëlle Char, Xavier Frogneux, Thibault Cantat. Synthesis of Aromatic Sulfones from SO 2 and Organosilanes Under Metal-free Conditions. Angewandte Chemie, 2017, 129 (20), pp.5708 - 5711. ⟨10.1002/ange.201702311⟩. ⟨cea-01659794⟩