Uranium Extraction by a Bifunctional Amido-Phosphonic Acid: Coordination Structure and Aggregation

Abstract : Butyl-N,N-di(2-ethylhexyl)carbamoyl-nonylphosphonate (DEHCNPB) is a new amido-phosphonic acid bifunctional ligand with a high uranium extraction efficiency from wet phosphoric acid. In the present work, the DEHCNPB coordination structure toward uranium and its aggregation properties have been fully characterized using experimental and theoretical approaches. DEHCNPB forms associated species, and its aggregation properties such as aggregation number or CAC have been determined from SAXS and SANS measurements. The preferred site for bonding of DEHCNPB toward U(VI) has been determined from IR, EXAFS, and DFT calculations.
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Solvent Extraction and Ion Exchange, Taylor & Francis, 2016, 34 (3), pp.260 - 273. 〈http://dx.doi.org/10.1080/07366299.2016.1169146〉. 〈10.1080/07366299.2016.1169146〉
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Soumis le : mardi 14 novembre 2017 - 10:43:18
Dernière modification le : jeudi 16 novembre 2017 - 01:09:45

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Olivia Pecheur, Dominique Guillaumont, Sandrine Dourdain, Laurence Berthon, Raphaël Turgis, et al.. Uranium Extraction by a Bifunctional Amido-Phosphonic Acid: Coordination Structure and Aggregation. Solvent Extraction and Ion Exchange, Taylor & Francis, 2016, 34 (3), pp.260 - 273. 〈http://dx.doi.org/10.1080/07366299.2016.1169146〉. 〈10.1080/07366299.2016.1169146〉. 〈cea-01634464〉

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