A Straightforward Access to Cyclotriveratrylene Analogues with C1-Symmetry: Toward the Synthesis of Monofunctionalizable Cryptophanes

Gaëlle Milanole; Grégory Pieters; Bo Gao; Emilie Mari; Bernard Rousseau; Patrick Berthault

A Straightforward Access to Cyclotriveratrylene Analogues with C1-Symmetry: Toward the Synthesis of Monofunctionalizable Cryptophanes

Gaëlle Milanole ¹ Grégory Pieters ^{1, *} Bo Gao ¹ Emilie Mari ² Bernard Rousseau ¹ Patrick Berthault ²

* Corresponding author

1 SCBM - Service de Chimie Bio-Organique et de Marquage

2 LSDRM - Laboratoire Structure et Dynamique par Résonance Magnétique (LCF)

NIMBE UMR 3685 - Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M)

Abstract : A straightforward and practical access to various C1-symmetric cyclotriveratrylene derivatives from a monohalogenated cyclotriphenolene is described. This unique scaffold can also be used as a precursor for the rapid construction of monofunctionalizable cryptophane-based biosensors for hyperpolarized $^{129}$Xe MRI.

Document type :

Journal articles

Domain :

Chemical Sciences / Material chemistry

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https://hal-cea.archives-ouvertes.fr/cea-01622050
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Submitted on : Tuesday, November 7, 2017 - 11:27:15 AM
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A Straightforward Access to Cyclotriveratrylene Analogues with C1-Symmetry: Toward the Synthesis of Monofunctionalizable Cryptophanes

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A Straightforward Access to Cyclotriveratrylene Analogues with C1-Symmetry: Toward the Synthesis of Monofunctionalizable Cryptophanes

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