Abstract : A straightforward and practical access to various C1-symmetric cyclotriveratrylene derivatives from a monohalogenated cyclotriphenolene is described. This unique scaffold can also be used as a precursor for the rapid construction of monofunctionalizable cryptophane-based biosensors for hyperpolarized $^{129}$Xe MRI.
https://hal-cea.archives-ouvertes.fr/cea-01622050
Contributor : Serge Palacin
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Submitted on : Tuesday, November 7, 2017 - 11:27:15 AM
Last modification on : Thursday, March 7, 2019 - 3:34:14 PM
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Gaëlle Milanole, Grégory Pieters, Bo Gao, Emilie Mari, Bernard Rousseau, et al.. A Straightforward Access to Cyclotriveratrylene Analogues with C1-Symmetry: Toward the Synthesis of Monofunctionalizable Cryptophanes. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2017, 47, pp.7091-7100. ⟨http://dx.doi.org/10.1002/ejoc.201701353⟩. ⟨10.1002/ejoc.201701353⟩. ⟨cea-01622050⟩
